Filament comparison
PA blend vs TPE SEBS
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | TPE (SEBS)FLEX |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $98.25/kg median; $76.50–$120.00/kg across 2 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | Styrene-ethylene-butadiene-styrene thermoplastic elastomer — a styrenic rubber, not a polyurethane[3] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.044 printed part density (BASF Ultrafuse TPS 90A, ISO 1183-1) — the lightest elastomer here[3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[4][5][6] | 1 kg-equivalent spools cluster near 77[7] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[4][8][5][6] | 77 for the Recreus 600 g spool; Proto-pasta only lists a 50 g coil, which prices at 120[7][9] |
| Market availability1–5 | Available from several mainstream brands[4][8] | Niche, a handful of specialist brands[3][9][7] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[4][8][5][6] | 1.75 and 2.85 mm; 0.05 and 0.6 kg spools[3][7] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Soft-touch overmoulds and skin-contact parts where a non-polyurethane elastomer is wanted[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | 260–280 (BASF Ultrafuse TPS 90A) — far hotter than any TPU here[3] |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 70–90 (BASF Ultrafuse TPS 90A)[3] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Open frame is fine[3] |
| Bed surface & adhesion aid | Not documented | PEI sheet or painter's tape; Polymaker warns TPU can over-stick and advises a glue stick as a release agent[10][11] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][12] | 0.8–2.4 at the 10–30 mm/s BASF specifies on a 0.4 mm nozzle at 0.2 mm layer — the slowest material in this group[3] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][13] | Advanced — enclosure, hardware upgrades, tuning[3] |
| Extruder requirement | Not documented | Nozzle 0.4 mm or larger; BASF caps print speed at 10–30 mm/s[3] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[14] | Brass fine indefinitely[15] |
| Abrasiveness1–5 | Non-abrasive when unfilled[14] | Non-abrasive[15] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[16][13] | Moderate — needs dry filament and a clean nozzle; BASF caps print speed at 10–30 mm/s and Simplify3D warns that raised feed rates on flexibles most likely end in a jam[10][3] |
| Hotend requirement | Not documented | No special hot-end required, but a direct-drive extruder is (Simplify3D)[10] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][13] | Negligible (<0.1 % EMC) — BASF states drying is not necessary, unique among the elastomers here[3] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | None — BASF states Ultrafuse TPS 90A arrives in a printable condition and drying is not necessary[3] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[16] | Bubbling and popping at the nozzle, stringing and a rough surface[13] |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][16] | Not applicable — the SEBS chemistry has no amide or ester linkages to take up water, and BASF specifies no drying at all[3] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | Sealed with desiccant; often kept in a dryer during the print[13] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][17] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | Not documented |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Very ductile — bends far before failing[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[18] | 89 Shore A and 29 Shore D (BASF Ultrafuse TPS 90A, ISO 7619-1)[3] |
| Creep resistance / sustained load1–5 | Not documented | Poor — no SEBS creep test; a printed 95A TPU bar crept from 74.5 to 82.7 mm over 5 days at 1.25 kg[19] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[14] | Excellent — living hinges viable[11] |
| Elasticity / flexibility1–5 | Semi-flexible[16] | Rubbery / highly elastic[3] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | Not documented |
| Wear resistance & friction | Not documented | Abrasion 111 mm³ (ISO 4649) — the poorest abrasion resistance in this group, well behind TPU[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | Not documented |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | Not documented |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | Not documented |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | 242–249 melting (BASF Ultrafuse TPS 90A, ISO 11357-3)[3] |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Not documented |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[18] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift; Polymaker lists UV exposure among the conditions TPU withstands[11] |
| Chemical resistance | Not documented | Withstands industrial solvents and UV exposure (Polymaker)[11] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Excellent — essentially unaffected[3] |
| Food contact | Not documented | Not food safe without specific certification (Polymaker)[11] |
| Biodegradability / compostability | Not documented | Not biodegradable[11] |
| Recyclability | Not documented | Not accepted in household plastic collection[11] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[20] | Low hazard — minimal VOC and particle emission; TPU was not among the nine filaments in the chamber study[20] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[20] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[20] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[20] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[20] | Open a window / occasional ventilation[20] |
| Post-Processing | ||
| Sanding & machining | Not documented | Difficult to sand or smooth; Polymaker limits post-processing to trimming or tumbling[11] |
| Gluing & solvent welding | Not documented | Cyanoacrylate bonds TPU; no common solvent welds it[11] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[11] |
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Polymaker warns TPU supports are often very difficult to remove[11] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[21] | Toluene dissolves SEBS at room temperature — Kraton quotes solution viscosity at 25 % mass in toluene, 25 °C.[22] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[21] | Soaking in hydrocarbon solvents and oils deteriorates it; short exposures are tolerated. Resists water, acids and bases.[22] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[21] | Toluene will weld it, though the joint stays soft; no workshop-safe agent, and vapour smoothing is not practical.[22] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- Ultrafuse TPS 90A Technical Data Sheet (Version 1.1, SEBS) BASF Forward AM · 2020-12 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- Recreus product catalogue Recreus · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- Flexible (TPE/TPU) — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- TPU — material basics Polymaker Wiki · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- BambuLab TPU 95A HF vs Qidi TPU 95A HF — results spreadsheet My Tech Fun (Igor Gaspar) · 2024-02 · test
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- KRATON polymers Grade Range — chemical resistance and toluene solution data Kraton Corporation · 2025-07 · tds