Filament comparison
PA blend vs PP-GF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | Glass-fibre PP (PP-GF)POLYOLEFIN |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $49.09/kg median; $46.27–$86.01/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | Polypropylene reinforced with chopped glass fibre[3][4] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.12 (Prusament PP Glass Fiber, ISO 1183) — the glass lifts it above water[3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[5][6][7] | 1 kg-equivalent spools cluster near 49[8][9][10] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[5][11][6][7] | 46-86 across brands; BCN3D PP GF30 46 at 700 g, BASF Ultrafuse PP GF30 49 at 2.2 kg, Prusament PP Glass Fiber 86 at 850 g[8][9][10] |
| Market availability1–5 | Available from several mainstream brands[5][11] | Available from several mainstream brands[8][9][10] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[5][11][6][7] | 1.75 and 2.85 mm; 700 g, 850 g and 2.2 kg spools[8][9][10] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Stiff, chemically resistant parts where PP-CF's cost or conductivity is unwanted[4] |
| Diameter tolerance± mm | Not documented | ±0.04 (Prusament)[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | 245 ± 10 (Prusament) — 25 °C below the carbon-fibre grade[3][12] |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 95 ± 10 (Prusament)[3] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[13][14] |
| Part cooling fan | Not documented | Off — Prusa runs 0 % except 100 % on bridges[3] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][15] | 4 at Prusa's 50 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[3][15] |
| Warping tendency1–5 | Not documented | High — enclosure needed for reliable large parts; Prusa recommends a brim[3] |
| Bed-adhesion difficulty1–5 | Not documented | Very difficult — special plates or slurry required[3] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][16] | Advanced — enclosure, hardware upgrades, tuning; hardened nozzle mandatory[3] |
| Extruder requirement | Not documented | Prusa states a hardened nozzle is necessary and recommends a brim[3] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[17] | Hardened steel required[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[17] | Highly abrasive — standard GF composite[3] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[18][16] | Moderate — needs dry filament and a clean nozzle; Prusa lists higher risk of nozzle clogging for glass-filled composites[19] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][16] | Low (0.1–0.3 %) — 0.11 % at both 24 h and 7 days, higher than the carbon-fibre grade's 0.04 % but still very low[3][12] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.11 after 24 h and 0.11 after 7 days at 24 °C / 22 % RH (Prusa Polymers)[3] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | Not documented |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[18] | Not documented |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][18] | Not applicable in practice at 0.11 % equilibrium uptake[3] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | No special storage needed[3] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][20] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | 46.6 ± 1.3 filament tensile yield (Prusament, ISO 527) — more than double the carbon-fibre grade's 21[3][12] |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | 7.9 ± 0.4 printed horizontal and 9.9 ± 0.8 printed vertical XZ (ISO 179-1, notched)[3] |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Moderate[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[21] | Rockwell R102 (and M95) on extruded unfilled PP stock (ASTM D785); no figure is published for a glass-fibre PP filament[22] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[17] | Not documented |
| Elasticity / flexibility1–5 | Semi-flexible[18] | Rigid[3] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | 138.3 (ISO 75, 0.45 MPa)[3] |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | 112.6 (ISO 75, 1.8 MPa)[3] |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | Not documented |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | Not documented |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Not documented |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[21] | Not documented |
| Environment & Chemical | ||
| Chemical resistance | Not documented | Excellent against acids, alkalis and most solvents[14] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Excellent — essentially unaffected[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[23] | Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[23] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[23] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[23] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[23] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[23] | Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[23] |
| Dust & fibre handling hazard | Not documented | Glass fibre is bound in the matrix; avoid inhaling sanding dust[3] |
| Post-Processing | ||
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[24] | None at room temperature; chloroform dissolves the matrix at 60 °C and xylene at about 118 °C, leaving the fibre.[25][26] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[24] | Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[25] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[24] | None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[25] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Prusament PP Glass Fiber — material page Prusa Polymers · 2026-08 · doc
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- BASF Ultrafuse PP GF30 Black 2.85 mm 2.200 g igo3d · 2026-08 · vendor
- BCN3D PP GF30 Black 2.85 mm 700 g igo3d · 2026-08 · vendor
- Prusa Prusament PP Glass Fiber Natural (NFC), 1.75 mm / 850 g 3DJAKE · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- PP — material basics Polymaker Wiki · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
- US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper