3D Printing Info

Filament comparison

PA blend vs PP-CF

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA blend vs PP-CF — documented properties and sources
PropertyPA6/66 copolymer blendsPACarbon-fibre PP (PP-CF)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$65.62/kg median; $62.00–$113.33/kg across 4 dated product listings$107.68/kg median; $57.13–$120.00/kg across 3 dated product listings
Identity & Market
Base polymer / chemistryPA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2]Polypropylene reinforced with chopped carbon fibre[3][4]
Densityg/cm³1.12 (ISO 1183, Polymaker CoPA)[1]0.91 (Prusament PP Carbon Fiber, ISO 1183)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 65[5][6][7]1 kg-equivalent spools span 57–138; the middle of the market is about 108[8][9][10]
Price range across brandsUSD/kg62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[5][9][6][7]57–138 across brands; Reli3D 57 at 700 g on Amazon, Prusament 108 direct from Prusa and 138 at Printed Solid, 3DXTech CarbonX PP+CF 120[8][11][9][10]
Market availability1–5Available from several mainstream brands[5][9]Available from several mainstream brands[9][11]
Spool sizes & diameters1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[5][9][6][7]1.75 mm; 0.65 kg spools[11][9]
Typical applicationsGeneral-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1]Lightweight chemical-resistant parts, automotive clips and ducting that must survive above 150 °C[12]
Diameter tolerance± mmNot documented±0.04 (Prusament)[3]
Printing Parameters
Nozzle temperature°C250–270 (Polymaker CoPA)[1]270 ± 10 (Prusament)[3]
Bed temperature°C25–50 (Polymaker CoPA)[1]85 ± 10 (Prusament)[3]
Enclosure / chamber requirement1–5Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1]Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[13][14]
Part cooling fanNot documentedOff — Prusa runs 0 % except 100 % on bridges[3]
Maximum volumetric flow (mm³/s; see test conditions)mm³/s16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][15]3.2 at Prusa's 40 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[3][15]
Warping tendency1–5Not documentedHigh — enclosure needed for reliable large parts; Prusa recommends a brim[3]
Bed-adhesion difficulty1–5Not documentedVery difficult — special plates or slurry required[3]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][16]Advanced — enclosure, hardware upgrades, tuning; hardened nozzle mandatory[3]
Extruder requirementNot documentedPrusa states a hardened nozzle is necessary and recommends a brim[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[17]Hardened steel required — Prusa states plainly that a hardened nozzle is necessary[3]
Abrasiveness1–5Non-abrasive when unfilled[17]Highly abrasive — standard CF composite[3]
Nozzle clog risk1–5Very high — frequent jams without careful setup[18][16]Moderate — needs dry filament and a clean nozzle; 3DXTech specifies a hardened 0.4 mm minimum nozzle and 0.25 mm layers or higher, and Prusa lists composites as a higher clogging risk[4][19]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][16]Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[3]
Equilibrium moisture content at ~50 % RH%Not documented0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers)[3]
Drying temperature & time100 °C for 8 h (Polymaker CoPA)[1]Not documented
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[18]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][18]Not applicable in practice at 0.04 % equilibrium uptake[3]
Storage requirementPolymaker states CoPA must always be stored and used below 20 % relative humidity[1]No special storage needed[3]
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][20]Not documented
Mechanical Properties
Tensile strength (XY)MPa78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1]21 ± 0.4 filament tensile yield (Prusament, ISO 527)[3]
Young's modulusMPa2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1]Not documented
Elongation at break%12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1]Not documented
Flexural strengthMPa109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1]Not documented
Flexural modulusMPa2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1]Not documented
Charpy impact, notchedkJ/m²6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1]14.5 ± 0.3 printed horizontal and 10.5 ± 0.8 printed vertical XZ (ISO 179-1, notched)[3]
Layer adhesion / Z tensileMPa45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1]Not documented
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Tough — absorbs impact, yields before breaking[3]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[21]Rockwell R102 (and M95) on extruded unfilled PP stock (ASTM D785); no figure is published for a carbon-fibre PP filament[22]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[17]Good[23]
Elasticity / flexibility1–5Semi-flexible[18]Slightly flexible in thin sections[3]
Z strength as % of XY%59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1]Not documented
Thermal Properties
HDT at 0.45 MPa°C111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1]158 (ISO 75, 0.45 MPa) — far above unfilled PP and above most engineering filaments[3]
HDT at 1.8 MPa°C70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1]115 (ISO 75, 1.8 MPa)[3]
Glass transition (Tg)°C66 (DSC, Polymaker CoPA)[1]Not documented
Melting point / Vicat°C189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1]Not documented
Annealing response80 °C for 6 h (Polymaker CoPA)[1]Not documented
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[21]Not documented
Environment & Chemical
Chemical resistanceNot documentedExcellent against acids, alkalis and most solvents[14]
Water / humidity resistance in service1–5Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1]Excellent — essentially unaffected[3]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[24]Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[24]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[24]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[24]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[24]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[24]Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[24]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[3]
Post-Processing
Support material pairingCoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1]Not documented
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[25]None at room temperature; chloroform dissolves the matrix at 60 °C and xylene at about 118 °C, leaving the fibre.[26][27]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[25]Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[26]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[25]None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[26]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  2. AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
  3. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  4. CarbonX PP+CF — product page 3DXTech · 2026-08 · vendor
  5. Polymaker product catalogue Polymaker · 2026-08 · vendor
  6. add:north Adura product page add:north · 2026-08 · vendor
  7. PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
  8. Prusament PP Carbon Fiber Black 650g — product page Prusa Research · 2026-08 · vendor
  9. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  10. Reli3D Carbon Fiber PP Filament 1.75 mm 700 g Black — Amazon listing Amazon.com · 2026-08 · vendor
  11. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  12. Prusament PP Carbon Fiber — material page Prusa Polymers · 2026-08 · doc
  13. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  14. PP — material basics Polymaker Wiki · 2026-08 · doc
  15. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  16. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  17. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  18. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  19. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  20. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  21. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  22. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  23. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  24. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  25. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  26. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  27. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper