Filament comparison
PA blend vs PETG-ESD
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | ESD-safe PETGPETG |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $102.99/kg median; $65.98–$140.00/kg across 2 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | PETG compounded with a conductive filler to bring surface resistivity into the static-dissipative range[3][4] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.24 (Fiberon) and 1.28 (3DXTech), ISO 1183[3][4] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[5][6][7] | 1 kg-equivalent spools span 66–140; the middle of the market is about 103[5][8] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[5][8][6][7] | 66–140 across brands; Fiberon PETG-ESD 66, 3DXSTAT ESD-PETG 140[5][8] |
| Market availability1–5 | Available from several mainstream brands[5][8] | Niche, a handful of specialist brands[5][8] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[5][8][6][7] | 1.75 mm; 0.5, 0.75, 1 and 3 kg spools[5][8] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Electronics fixtures, trays and jigs handled around static-sensitive components[3][4] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | 250–290 (Fiberon)[3] |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 70–80 (Fiberon); 70 (3DXTech)[3][4] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Open frame is fine — Fiberon specifies room-temperature chamber[3] |
| Bed surface & adhesion aid | Not documented | Textured PEI, satin or powder-coated sheets; on smooth PEI a glue stick acts as a release agent[9][10] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][11] | Fiberon rates the material to 500 mm/s, equivalent to 40 on a 0.4 mm nozzle at 0.2 mm layer — a machine-limited headline rather than a measured melt rate[3][11] |
| Bed-adhesion difficulty1–5 | Not documented | Needs the right surface or a thin adhesive — the problem is releasing the part, not sticking it[9][10] |
| Stringing / oozing tendency1–5 | Not documented | Moderate — retraction tuning needed; Polymaker names stringing as PETG's common quirk[10] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][12] | Intermediate — dry filament and a tuned profile; resistivity depends on getting the nozzle temperature right[3] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[13] | Hardened steel required[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[13] | Moderately abrasive — conductive carbon filler[3] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[14][12] | Low — 3DXTech lists no special nozzle concerns and no minimum layer height for its ESD-PETG, only a 65 °C pre-dry[15] |
| Heat-creep / jam sensitivity1–5 | Not documented | Slightly sensitive[16] |
| Hotend requirement | Not documented | No special hot-end required[16] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][12] | Moderate (0.3–0.8 %) — the PETG matrix reaches 0.40 % saturated at 25 °C / 55 % RH and 3DXTech specifies a 65 °C, 4 h pre-dry[9][15] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.41 equilibrium water absorption (Fiberon PETG-ESD)[3] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | 65 °C for 3 h (Fiberon)[3] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[14] | Bubbling and popping at the nozzle, stringing and a rough surface[12] |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][14] | Polymaker groups PETG with nylon, PVA and TPU as highly hygroscopic; no dry-versus-conditioned strength figures are published for this grade and the loss shows as bubbling and poor layer adhesion[12] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | Sealed with desiccant; Polymaker groups PETG with the highly hygroscopic materials[12][10] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][17] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | 36.1 ± 0.9 printed XY, ISO 527 (Fiberon); 3DXTech quotes 50 at break[3][4] |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | 1983 ± 75 printed XY, ISO 527 (Fiberon)[3] |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | 7.3 ± 0.7 printed XY, ISO 527 (Fiberon); 3DXTech quotes 13 at break[3][4] |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | 54.0 ± 2.5 printed XY, ISO 178 (Fiberon)[3] |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | 1651 ± 141 printed XY, ISO 178 (Fiberon)[3] |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | 5.7 ± 0.5 printed XY, ISO 179, notched (Fiberon)[3] |
| Other impact data | Not documented | Charpy unnotched 29.3 ± 2.2 printed XY (Fiberon, ISO 179)[3] |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | 20.7 ± 0.6 printed Z, ISO 527 (Fiberon)[3] |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Moderate[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[18] | Not documented |
| Creep resistance / sustained load1–5 | Not documented | Below average — no ESD-grade creep test; unfilled PETG sagged from 12 to 17.1–20.4 mm over 5 days at 1.25 kg[19][20][21][22] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[13] | Moderate — no ESD-grade S-N curve; unfilled printed PETG ran 79 000–193 000 cycles at 30 % of tensile strength[23] |
| Elasticity / flexibility1–5 | Semi-flexible[14] | Slightly flexible in thin sections[3] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | 57 (Fiberon, printed Z against XY tensile)[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | 76 (ISO 75, 0.45 MPa, Fiberon)[3] |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | 72 (ISO 75, 1.8 MPa, Fiberon)[3] |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | 77 (Fiberon) and 80 (3DXTech), DSC[3][4] |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | Amorphous — no melting point; Vicat 86 (Fiberon, ISO 306)[3] |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Not documented |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[18] | Not documented |
| Flammability / UL 94 | Not documented | Flammable; no UL 94 rating published for standard grades[24] |
| Environment & Chemical | ||
| Chemical resistance | Not documented | Withstands acids, alkalis, oils and UV exposure[10] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Not documented |
| Food contact | Not documented | Not certified for food contact as filament[10] |
| Biodegradability / compostability | Not documented | Not biodegradable[10] |
| Recyclability | Not documented | Not accepted in household plastic collection[10] |
| Electrical & ESD properties | Not documented | Surface resistivity falls with nozzle temperature: 7.0×10⁶–1.6×10⁷ ohm at 250 °C, 3.2×10⁵–4.7×10⁵ at 270 °C and below 1×10⁴ at 290 °C (Fiberon); 3DXTech quotes 10⁷–10⁹ ohm/sq[3][4] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[25] | Moderate — measurable VOCs and UFPs, ventilation advised[25] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[25] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[25] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[25] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[25] | Open a window / occasional ventilation[25] |
| Dust & fibre handling hazard | Not documented | Conductive carbon filler is bound in the matrix; avoid inhaling sanding dust[3] |
| Post-Processing | ||
| Sanding & machining | Not documented | Sands poorly — the material is tough and gums rather than powders[16] |
| Gluing & solvent welding | Not documented | Cyanoacrylate; no common solvent welds PETG cleanly[16] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[16] |
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Prints its own supports; Polymaker rates PolyDissolve S1 for PETG[16] |
| Dimensional accuracy & detail | Not documented | Nozzle temperature has to be held steady — it moves surface resistivity by three orders of magnitude[3] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[26] | No common workshop solvent; 1,2-dichloroethane destroys it inside a week and dichloromethane — a carcinogen — dissolves the surface.[27][28] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[26] | Acetone (+16 % weight over 1 year at 23 °C), ethyl acetate, toluene and DMF swell and soften it; methanol crazes it.[27] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[26] | Dichloromethane brushed on is the only agent that smooths PETG — a controlled carcinogen, not workshop stock.[28] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- Fiberon PETG-ESD Technical Data Sheet V1.1 Polymaker · 2026-08 · tds
- 3DXSTAT ESD-PETG Technical Data Sheet 3DXTech · 2026-08 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Prusament PETG Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- PETG — material basics Polymaker Wiki · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- 3DXSTAT ESD-PETG — product page (print recommendations) 3DXTech · 2026-08 · doc
- PET and PETG — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- PCTG vs PETG comparison — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Extrudr PETG vs PCTG vs XPETG-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Prusament PETG-CF vs PETG V0 vs PETG — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- BambuLab PETG Basic vs Translucent vs PETG-CF — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- Mechanical Properties of Additively Manufactured Polymeric Materials — PLA and PETG — For Biomechanical Applications Polymers 16(13):1868 · 2024-06 · paper
- Prusament PETG V0 Technical Datasheet Prusa Polymers · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Eastman Spectar copolyester — Chemical resistance (unstressed bars, 1 year at 23 °C) Eastman Chemical Company · 2026-08 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc