3D Printing Info

Filament comparison

PA blend vs PE

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA blend vs PE — documented properties and sources
PropertyPA6/66 copolymer blendsPAPolyethylene (PE)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$65.62/kg median; $62.00–$113.33/kg across 4 dated product listings$87.72/kg median; $87.72–$87.72/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2]Polyethylene — the simplest polyolefin, non-polar and highly crystalline. The one retailed filament grade, Spectrum HDPE, uses what Spectrum calls Low Warp technology and is denser and stiffer than plain HDPE[3][4]
Densityg/cm³1.12 (ISO 1183, Polymaker CoPA)[1]1.10 (Spectrum HDPE filament, ISO 1183) against 0.95 for extruded HDPE stock — the filament is a modified formulation[3][4]
Typical priceUSD/kg1 kg-equivalent spools cluster near 65[5][6][7]1 kg-equivalent spools cluster near 88[8]
Price range across brandsUSD/kg62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[5][9][6][7]87.72 — Spectrum's 500 g spools at 3DJAKE are the only PE filament listing found[8]
Market availability1–5Available from several mainstream brands[5][9]Niche, a handful of specialist brands — Spectrum HDPE in six colours is the only PE filament in the 3DJAKE and igo3d product sitemaps, at MatterHackers or at Printed Solid, but it is a normal stocked item rather than a special order[10][11][12][8]
Spool sizes & diameters1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[5][9][6][7]1.75 mm; 500 g spools in six colours[8][10]
Typical applicationsGeneral-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1]Chemically resistant containers, packaging prototypes and consumer goods where HDPE is the production material[3]
Printing Parameters
Nozzle temperature°C250–270 (Polymaker CoPA)[1]240-290 (Spectrum HDPE)[3]
Bed temperature°C25–50 (Polymaker CoPA)[1]80-100 (Spectrum HDPE)[3]
Enclosure / chamber requirement1–5Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1]Enclosure recommended — Spectrum recommends a closed chamber for larger prints[3]
Part cooling fanNot documented0-50 % part cooling (Spectrum HDPE)[3]
Bed surface & adhesion aidNot documentedSpectrum states no adhesive is necessary for its low-warp HDPE, depending on geometry[3]
Maximum volumetric flow (mm³/s; see test conditions)mm³/s16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][13]Not documented
Warping tendency1–5Not documentedModerate — needs adhesion aid or draught shield. Spectrum's low-warp grade is sold as printable on desktop machines, which is not true of plain polyethylene[3]
Bed-adhesion difficulty1–5Not documentedNeeds the right surface or a thin adhesive; Spectrum states no adhesive is necessary but recommends a closed chamber for large parts[3]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][14]Intermediate — dry filament and a tuned profile; Spectrum sells the grade as desktop-printable with no dry box and no hardened nozzle[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[15]Brass fine indefinitely — Spectrum states a ruby or hardened nozzle is not required[3]
Abrasiveness1–5Non-abrasive when unfilled[15]Non-abrasive[3]
Nozzle clog risk1–5Very high — frequent jams without careful setup[16][14]Low — Spectrum lists no drybox and no ruby or hardened nozzle for HDPE, and very low moisture absorption[3]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][14]Negligible (<0.1 % EMC) — Spectrum lists very low moisture absorption and no dry box[3]
Drying temperature & time100 °C for 8 h (Polymaker CoPA)[1]No drying step published; Spectrum lists a dry box as not required[3]
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[16]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][16]Not applicable in practice — Spectrum lists very low moisture absorption and no drybox requirement for HDPE[3]
Storage requirementPolymaker states CoPA must always be stored and used below 20 % relative humidity[1]Store dry at 18-25 °C out of sunlight; Spectrum quotes a 24-month shelf life[3]
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][17]Not documented
Mechanical Properties
Tensile strength (XY)MPa78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1]29 at break (Spectrum HDPE, ISO 527; specimen type not stated) against 25.5 at yield on extruded HDPE stock (ASTM D638, from 3700 psi)[3][4]
Young's modulusMPa2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1]3500 (Spectrum HDPE, ISO 527) against 965 on extruded HDPE stock (ASTM D638, from 140,000 psi) — the filament grade is nearly four times stiffer than plain polyethylene[3][4]
Elongation at break%12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1]18 at break (Spectrum HDPE, ISO 527) against above 100 on extruded stock (ASTM D638)[3][4]
Flexural strengthMPa109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1]27.6 on extruded HDPE stock (ASTM D790; converted from 4000 psi)[4]
Flexural modulusMPa2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1]3200 (Spectrum HDPE, ISO 178) against 965 on extruded stock (ASTM D790, from 140,000 psi)[3][4]
Charpy impact, notchedkJ/m²6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1]Not documented
Other impact dataNot documentedCharpy 10 kJ/m2 (Spectrum HDPE, ISO 179-1; notch condition not stated); Izod 104 J/m on extruded stock, converted from 1.94 ft-lb/in (ASTM D256)[3][4]
Layer adhesion / Z tensileMPa45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1]Not documented
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Tough — absorbs impact, yields before breaking; 18 % elongation at break on the filament and above 100 % on extruded stock[3][4]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[18]Shore D 67 and Rockwell R54 on extruded HDPE stock (ASTM D2240, D785); Spectrum quotes Rockwell 80 HRM for its filament (ISO 2039-2)[4][3]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[15]Good — Spectrum lists outstanding abrasion and crack resistance for its HDPE, but no repeated-flex or fatigue test data was found for any PE filament[3]
Elasticity / flexibility1–5Semi-flexible[16]Slightly flexible in thin sections — Spectrum's low-warp grade has a 3.5 GPa tensile modulus; plain extruded HDPE at 965 MPa is genuinely semi-flexible[3][4]
Z strength as % of XY%59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1]Not documented
Thermal Properties
HDT at 0.45 MPa°C111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1]75 on extruded HDPE stock (ASTM D648 at 66 psi; converted from 167 °F)[4]
HDT at 1.8 MPa°C70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1]Not documented
Glass transition (Tg)°C66 (DSC, Polymaker CoPA)[1]Not documented
Melting point / Vicat°C189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1]Not documented
Continuous service temperature°CNot documented110 stated as heat resistance by Spectrum with no test standard given; extruded stock is rated 120 long-term maximum (converted from 248 °F) and brittle below -76[3][4]
Annealing response80 °C for 6 h (Polymaker CoPA)[1]Not documented
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[18]117 (extruded HDPE stock, ASTM D696; source states 6.5e-5 in/in/°F)[4]
Environment & Chemical
UV resistance1–5Not documentedModerate — a season or two. Spectrum describes its HDPE as UV-stable and weather-resistant but publishes no exposure data[3]
Chemical resistanceNot documentedExcellent chemical resistance to acids, bases, oils and solvents (Spectrum); Ensinger lists broad chemical compatibility for HDPE stock[3][4]
Water / humidity resistance in service1–5Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1]Excellent — essentially unaffected; Ensinger lists low moisture absorption for HDPE stock and Spectrum very low absorption for the filament[3][4]
RecyclabilityNot documentedSpectrum states the filament is fully recyclable; HDPE is resin code 2[3]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[19]Not documented
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[19]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[19]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[19]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Not documented
Post-Processing
Sanding & machiningNot documentedEasy to machine — Ensinger lists machinability as a headline property of HDPE stock[4]
Support material pairingCoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1]Not documented
Dimensional accuracy & detailNot documentedSpectrum lists a shiny surface finish and no adhesive requirement; shrinkage remains the limit on large flat parts[3]
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[20]None at room temperature; xylene dissolves HDPE at about 105 °C and LDPE at 75 °C. Hot decalin does the same.[21][22]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[20]Toluene, xylene, styrene, chloroform, dichloromethane, MEK and trichloroethylene are all unsatisfactory at 21 °C.[22]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[20]None — polyethylene has no room-temperature solvent, so joints are made by heat welding.[22][21]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  2. AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
  3. Spectrum HDPE Technical Data Sheet Spectrum Filaments · 2025-10 · tds
  4. TECAFINE HDPE natural — stock shape properties Ensinger · 2026-08 · tds
  5. Polymaker product catalogue Polymaker · 2026-08 · vendor
  6. add:north Adura product page add:north · 2026-08 · vendor
  7. PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
  8. Spectrum HDPE Traffic Black, 1.75 mm / 500 g 3DJAKE · 2026-08 · vendor
  9. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  10. 3DJAKE product catalogue 3DJAKE · 2026-08 · vendor
  11. igo3d product sitemap (17452 product URLs) igo3d · 2026-08 · vendor
  12. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  13. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  14. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  15. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  16. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  17. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  18. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  21. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
  22. HDPE Chemical Resistance Guide (21 °C and 60 °C) INEOS Olefins & Polymers USA · 2026-08 · tds