Filament comparison
PA blend vs PA12
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA6/66 copolymer blendsPA | PA12 (Nylon 12)PA |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $65.62/kg median; $62.00–$113.33/kg across 4 dated product listings | $64.33/kg median; $36.00–$170.67/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | PA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2] | Polyamide 12 — the longest-chain common nylon, with the fewest amide groups per unit mass and so the least moisture uptake[3][4] |
| Densityg/cm³ | 1.12 (ISO 1183, Polymaker CoPA)[1] | 1.01 specific gravity (Stratasys FDM Nylon 12, ASTM D792)[5] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 65[6][7][8] | 1 kg-equivalent spools span 36–171; the middle of the market is about 64[9][10] |
| Price range across brandsUSD/kg | 62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[6][11][7][8] | 36–171 across brands; IEMAI 3D 36, Fiberlogy 64 at 3DJake, 3DXTech AmideX Nylon 12 171[9][11][10] |
| Market availability1–5 | Available from several mainstream brands[6][11] | Available from several mainstream brands[9][11] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[6][11][7][8] | 1.75 and 2.85 mm; 750 g and 1 kg spools[11][9] |
| Typical applications | General-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1] | Dimensionally stable functional parts, ducting and living hinges where PA6 would move too much with humidity[3][12] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Polymaker CoPA)[1] | 260–290 (Extrudr DURAPRO PA12)[13] |
| Bed temperature°C | 25–50 (Polymaker CoPA)[1] | 110 (Extrudr DURAPRO PA12)[13] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1] | Enclosure required (passive)[3] |
| Part cooling fan | Not documented | Part cooling fan not required (Simplify3D)[14] |
| Bed surface & adhesion aid | Not documented | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[14][3] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][15] | 12 at Extrudr's 150 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[13][15] |
| Bed-adhesion difficulty1–5 | Not documented | Needs a specific surface plus adhesive[14][3] |
| Stringing / oozing tendency1–5 | Not documented | Moderate — retraction tuning needed[3] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][16] | Advanced — enclosure, hardware upgrades, tuning[3] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[3] | Brass fine indefinitely for unfilled grades[3] |
| Abrasiveness1–5 | Non-abrasive when unfilled[3] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[12][16] | High — jams from moisture, heat creep or particles[12][16] |
| Heat-creep / jam sensitivity1–5 | Not documented | Moderate — good heatbreak cooling needed[14] |
| Hotend requirement | Not documented | May require an all-metal hot end (Simplify3D)[14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][16] | High (0.8–2 %) — Polymaker's PA12-CF10 reaches 1.5 % equilibrium against 3.33 % for its PA6-GF25, and Polymaker developed the PA12 grade specifically for lower moisture sensitivity[4][12] |
| Drying temperature & time | 100 °C for 8 h (Polymaker CoPA)[1] | 60–80 °C for 8–12 h (Extrudr DURAPRO PA12); 100 °C for 8 h (Polymaker CoPA)[13][1] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[12] | Popping and cracking during extrusion, then hard-to-diagnose defects[12] |
| Effect of moisture on strength | Measured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][12] | Polymaker states its PA12 grade changes little between wet and dry, unlike its PA6-based materials; the CoPA dry-to-wet reference shows what the PA6-type response looks like[12][1] |
| Storage requirement | Polymaker states CoPA must always be stored and used below 20 % relative humidity[1] | Sealed below 20 % RH with desiccant[16] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][17] | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][17] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1] | 49.3 at yield and 33.4 at break printed XZ (Stratasys FDM Nylon 12, ASTM D638)[5] |
| Young's modulusMPa | 2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1] | 1510 printed XZ and 1250 ZX (Stratasys FDM Nylon 12, ASTM D638)[5] |
| Elongation at break% | 12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1] | 30 at break printed XZ against 6.5 in ZX (Stratasys FDM Nylon 12, ASTM D638)[5] |
| Flexural strengthMPa | 109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Flexural modulusMPa | 2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1] | Not documented |
| Charpy impact, notchedkJ/m² | 6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1] | 11 at +23 °C and 6.0 at -30 °C (Extrudr DuraPro PA12, ISO 179/1eA); unnotched does not break[13] |
| Other impact data | Not documented | Izod notched 138 J/m printed XZ against 71.0 J/m in ZX (Stratasys FDM Nylon 12, ASTM D256)[5] |
| Layer adhesion / Z tensileMPa | 45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1] | 41.8 at yield and 41.2 at break printed ZX (Stratasys FDM Nylon 12, ASTM D638) — higher than the XZ break figure, because XZ specimens draw and neck first[5] |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Tough — absorbs impact, yields before breaking[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Shore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[18] | Not documented |
| Creep resistance / sustained load1–5 | Not documented | Moderate — the long-chain polyamides hold load better than PLA but below PC[3] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable[3] | Excellent — living hinges viable. Stratasys sells FDM Nylon 12 specifically for repetitive-flex parts such as snap-fit clips and press-fit inserts on the strength of its fatigue properties[3][5] |
| Elasticity / flexibility1–5 | Semi-flexible[12] | Semi-flexible[12] |
| Z strength as % of XY% | 59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1] | 85 (Stratasys FDM Nylon 12, ZX against XZ tensile yield, ASTM D638) — one of the least anisotropic unfilled filaments measured[5] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1] | 94.7 printed XY and 91.9 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 66 psi)[5] |
| HDT at 1.8 MPa°C | 70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1] | 84.3 printed XY and 75.3 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 264 psi)[5] |
| Glass transition (Tg)°C | 66 (DSC, Polymaker CoPA)[1] | 34.0 (Stratasys FDM Nylon 12, ASTM D7426 inflection point)[5] |
| Melting point / Vicat°C | 189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1] | Vicat A 142 (Extrudr DURAPRO PA12, ISO 306)[13] |
| Continuous service temperature°C | Not documented | Bounded by a Vicat softening point of 142 °C (Extrudr DURAPRO PA12); no loaded-bar service figure is published[13] |
| Annealing response | 80 °C for 6 h (Polymaker CoPA)[1] | Not documented |
| Thermal expansion (CTE)µm/m·K | 81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[18] | 84-103 printed (Stratasys FDM Nylon 12, ASTM E831: 84.4 in XY and 85.6 in XZ/ZX over -50 to 10 °C, 89.1 over 10-45 °C, 98.2 over 45-70 °C); Extrudr quotes 100 for DURAPRO PA12 (ISO 11359-2)[13][5] |
| Flammability / UL 94 | Not documented | Flammable; no UL 94 rating published for the unfilled grades surveyed[13] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Months outdoors before embrittlement[3] |
| Chemical resistance | Not documented | Withstands oils, fuels and alkalis[3] |
| Water / humidity resistance in service1–5 | Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1] | Good — minor absorption; the least moisture-sensitive of the common nylons[12] |
| Food contact | Not documented | Not food-contact certified as filament[3] |
| Biodegradability / compostability | Not documented | Not biodegradable[3] |
| Recyclability | Not documented | Mechanically recyclable but not accepted in household plastic collection[3] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[19] | Moderate — measurable VOCs and UFPs, ventilation advised[19] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[19] | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[19] |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[19] | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[19] |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[19] | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[19] |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[19] | Ventilated room or enclosure recommended[19] |
| Post-Processing | ||
| Sanding & machining | Not documented | Sands poorly — gums rather than powders[14] |
| Gluing & solvent welding | Not documented | Cyanoacrylate; no common solvent welds polyamide[14] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[14] |
| Support material pairing | CoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1] | Polymaker sells a break-away PolySupport matched to PA12[14] |
| Dimensional accuracy & detail | Not documented | Holds dimensions better than PA6 after conditioning — Polymaker singles its PA12 grade out on exactly this point[12] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[20] | Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[20][21] |
| Softened or crazed by | Zinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[20] | Not resistant to 10 % formic acid, phenol, chloroform or dichloromethane (Ensinger); zinc chloride stress-cracks nylon.[21][20] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[20] | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[20] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- FDM Nylon 12 — Material Data Sheet Stratasys · 2021-09 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- add:north Adura product page add:north · 2026-08 · vendor
- PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
- Nylon PA12 — product listing 3DJake International · 2026-08 · vendor
- IEMAI 3D PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds