3D Printing Info

Filament comparison

PA blend vs PA-CF ESD

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA blend vs PA-CF ESD — documented properties and sources
PropertyPA6/66 copolymer blendsPAESD-safe CF nylonPA
Market snapshot
Listing priceUSD/kg; dated snapshots$65.62/kg median; $62.00–$113.33/kg across 4 dated product listings$129.98/kg median; $129.98–$129.98/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryPA6/66 copolymer — a nylon alloy that lowers the melting point and improves printability against straight PA6[1][2]Carbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[3]
Densityg/cm³1.12 (ISO 1183, Polymaker CoPA)[1]1.10 (ISO 1183)[3]
Typical priceUSD/kg1 kg-equivalent spools cluster near 65[4][5][6]1 kg-equivalent spools cluster near 130[4]
Price range across brandsUSD/kg62–113 across brands; add:north Adura 62, PrimaCreator NylonPower PA6/66 65 at 500 g, Polymaker CoPA 67, 3DXTech AmideX Nylon 6-66 113[4][7][5][6]130 at Polymaker's 0.5 kg pricing[4]
Market availability1–5Available from several mainstream brands[4][7]Special order, 1–2 makers worldwide[4]
Spool sizes & diameters1.75 and 2.85 mm; 0.5, 0.75 and 1 kg spools[4][7][5][6]1.75 mm; 0.5 kg spools[4]
Typical applicationsGeneral-purpose nylon parts and, unusually, CoPA can support itself if the support is removed before it absorbs moisture[1]Electronics jigs and trays that also need nylon toughness and heat resistance[3]
Printing Parameters
Nozzle temperature°C250–270 (Polymaker CoPA)[1]Not documented
Bed temperature°C25–50 (Polymaker CoPA)[1]Not documented
Enclosure / chamber requirement1–5Enclosure required (passive) — Polymaker specifies a chamber at ambient temperature[1]Enclosure required (passive)[8]
Bed surface & adhesion aidNot documentedPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[9][8]
Maximum volumetric flow (mm³/s; see test conditions)mm³/s16 at Polymaker's 200 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[1][10]Not documented
Bed-adhesion difficulty1–5Not documentedNeeds a specific surface plus adhesive[9]
Stringing / oozing tendency1–5Not documentedModerate — retraction tuning needed[8]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; must be kept below 20 % RH throughout[1][11]Expert / industrial hardware only[8][11]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[8]Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[3]
Abrasiveness1–5Non-abrasive when unfilled[8]Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[3]
Nozzle clog risk1–5Very high — frequent jams without careful setup[12][11]High — jams from moisture, heat creep or particles[11]
Heat-creep / jam sensitivity1–5Not documentedModerate — good heatbreak cooling needed[9]
Hotend requirementNot documentedMay require an all-metal hot end (Simplify3D)[9]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker's own wet-state specimens reached 6.16 % moisture content after 48 h immersion at 60 °C[1][11]High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[13][12]
Drying temperature & time100 °C for 8 h (Polymaker CoPA)[1]Not documented
Symptoms when wetPopping and cracking during extrusion, then hard-to-diagnose defects[12]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[1][12]Polymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[3][12]
Storage requirementPolymaker states CoPA must always be stored and used below 20 % relative humidity[1]Sealed below 20 % RH with desiccant[11]
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[1][14]Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[15][1]
Mechanical Properties
Tensile strength (XY)MPa78.0 ± 0.7 printed XY dry and 34.3 ± 2.5 wet, ISO 527 (Polymaker CoPA)[1]84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[3]
Young's modulusMPa2703 ± 259 printed XY dry and 724 ± 61 wet, ISO 527 (Polymaker CoPA)[1]4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[3]
Elongation at break%12.7 ± 2.1 printed XY dry and 13.2 ± 2.3 wet, ISO 527 (Polymaker CoPA)[1]3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[3]
Flexural strengthMPa109.8 ± 1.3 printed XY dry and 22.6 ± 0.5 wet, ISO 178 (Polymaker CoPA)[1]Not documented
Flexural modulusMPa2510 ± 25 printed XY dry and 636 ± 11 wet, ISO 178 (Polymaker CoPA)[1]Not documented
Charpy impact, notchedkJ/m²6.9 ± 1.4 printed XY dry and 27.7 ± 1.2 wet, ISO 179 notched (Polymaker CoPA) — impact quadruples when conditioned[1]5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[3]
Other impact dataNot documentedCharpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[3]
Layer adhesion / Z tensileMPa45.8 ± 1.5 printed Z dry, falling to 13.7 ± 1.2 wet, ISO 527 (Polymaker CoPA)[1]21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[3]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[3]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785)[16]Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[17]
Creep resistance / sustained load1–5Not documentedGood. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[18][3]
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[8]Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[18]
Elasticity / flexibility1–5Semi-flexible[12]Rigid[3]
Z strength as % of XY%59 dry (45.8 Z against 78.0 XY) and 40 wet, printed[1]26 (printed Z against XY tensile)[3]
Thermal Properties
HDT at 0.45 MPa°C111 (ISO 75, 0.45 MPa, Polymaker CoPA)[1]157.0 (ISO 75, 0.45 MPa)[3]
HDT at 1.8 MPa°C70 (ISO 75, 1.8 MPa, Polymaker CoPA)[1]125.4 (ISO 75, 1.8 MPa)[3]
Glass transition (Tg)°C66 (DSC, Polymaker CoPA)[1]41.8 (DSC)[3]
Melting point / Vicat°C189 melting (DSC); Vicat 180, crystallisation 148, decomposition 370 (Polymaker CoPA)[1]187.3 melting (DSC); Vicat 190.0 (ISO 306)[3]
Annealing response80 °C for 6 h (Polymaker CoPA)[1]Not documented
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F) — the same chemistry as a PA6/66 copolymer[16]Not documented
Flammability / UL 94Not documentedFlammable; no UL 94 rating published for the grades surveyed[15]
Environment & Chemical
UV resistance1–5Not documentedMonths outdoors before embrittlement — unstabilised polyamide yellows under UV[8]
Chemical resistanceNot documentedWithstands oils, fuels and alkalis[8]
Water / humidity resistance in service1–5Absorbs water, properties shift — 6.16 % uptake cost 56 % of tensile strength and 73 % of modulus[1]Not documented
Food contactNot documentedNot food-contact certified as filament[8]
Biodegradability / compostabilityNot documentedNot biodegradable[8]
RecyclabilityNot documentedNot accepted in household plastic collection[8]
Electrical & ESD propertiesNot documentedStatic-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[3][13]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[19]Moderate — measurable VOCs and UFPs, ventilation advised[19]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[19]Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[19]
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[19]≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[19]
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[19]Caprolactam, at up to 180 µg/min from nylon filament[19]
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Ventilated room or enclosure recommended[19]
Dust & fibre handling hazardNot documentedFibre is bound in the matrix; sanding dust should not be inhaled[15]
Post-Processing
Sanding & machiningNot documentedSands poorly — gums rather than powders[9]
Gluing & solvent weldingNot documentedCyanoacrylate; no common solvent welds polyamide[9]
Vapour / chemical smoothingNot documentedNo practical vapour smoothing[9]
Support material pairingCoPA can support itself, but Polymaker warns the support bonds permanently if it absorbs moisture before removal[1]Not documented
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[20]Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[20]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[20]Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[20]
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[20]None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[20]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  2. AmideX Nylon 6-66 — product page 3DXTech · 2026-08 · vendor
  3. Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
  4. Polymaker product catalogue Polymaker · 2026-08 · vendor
  5. add:north Adura product page add:north · 2026-08 · vendor
  6. PrimaCreator SELECT NylonPower PA6/66 product page PrimaCreator · 2026-08 · vendor
  7. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  8. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  9. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  10. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  11. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  12. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  13. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  14. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  15. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  16. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  17. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  18. TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds