3D Printing InfoFilament comparison
PA aramid vs PPA
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Aramid-fibre nylonPA | PPA (polyphthalamide)PA |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | Not documented | $45.49/kg median; $45.49–$45.49/kg across 1 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Aramid-fibre reinforced polyamide[1] | Polyphthalamide — a semi-aromatic polyamide in which aromatic diacid units replace part of the aliphatic backbone; Raise3D and Bambu Lab both label it high-temperature nylon[2][3] |
| Densityg/cm³ | Not documented | 1.21 (ISO 1183, Siraya Tech Fibreheart PPA)[4] |
| Typical priceUSD/kg | Not documented | One 1 kg listing on the market, at 45[5] |
| Price range across brandsUSD/kg | Not documented | 45 for the only unfilled PPA filament found — Siraya Tech Fibreheart PPA at 1 kg; every other PPA in retail is carbon- or glass-filled[5] |
| Market availability1–5 | Special order, 1–2 makers worldwide — no aramid-filled nylon filament was found in any catalogue searched; the aramid filaments that do exist in the retail market use an ASA matrix[6][7] | Special order, 1–2 makers worldwide — Siraya Tech is the only brand found selling unfilled PPA filament[5] |
| Spool sizes & diameters | Not documented | 1.75 mm, 1 kg[5] |
| Typical applications | Not documented | Gears, bearings and tooling that must hold load above the reach of PA6 or PA12, and parts exposed to fuels and industrial chemicals[4] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 280–300 (Siraya Tech)[4] |
| Bed temperature°C | Not documented | 70–80 (Siraya Tech)[4] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — as for every nylon[1] | Enclosure recommended — Siraya Tech advises an enclosure to hold temperature and limit warping on larger prints[4] |
| Part cooling fan | Not documented | 20–60 % (Siraya Tech)[4] |
| Bed surface & adhesion aid | Not documented | PEI sheet with a glue stick, or a PVP glue coating[4] |
| Overall printing difficulty1–5 | Not documented | Advanced — enclosure, hardware upgrades, tuning; needs a 300 °C-class hot end and a dry spool[4] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — no aramid-filled nylon datasheet was obtainable; Polymaker measures about 9 h of brass nozzle life on its fibre-filled nylons[8] | Brass fine indefinitely — Siraya Tech states a hardened steel nozzle is not needed for the unfilled grade[4] |
| Abrasiveness1–5 | Highly abrasive — fibre-reinforced nylon composite[8] | Non-abrasive when unfilled[4] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles; nylon already needs a drybox and Prusa names kevlar among the fibres that raise nozzle-clogging risk[9] | Moderate — needs dry filament and a clean nozzle; Siraya Tech tells users to dry only when moisture symptoms appear, rather than before every print[4] |
| Hotend requirement | Not documented | High-quality metal nozzle, 0.4–1.0 mm; hardened steel not required (Siraya Tech)[4] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — the polyamide matrix governs uptake[10] | High (0.8–2 %) — Siraya Tech publishes 2.59 % by ISO 62 immersion for the unfilled grade; on the equilibrium basis Bambu Lab uses, its 15 % carbon-filled PPA reaches 1.30 % against 2.35 % for the same maker's PA6-CF[4][3][11] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 2.59 by ISO 62 water immersion (Siraya Tech, unfilled) — an immersion figure, not the 25 °C / 55 % RH equilibrium basis the filled grades are quoted on, so the two are not directly comparable[4] |
| Drying temperature & time | Not documented | 80–100 °C for 4–6 h (Siraya Tech)[4] |
| Symptoms when wet | Not documented | Oozing, bubbles and a rough surface finish (Siraya Tech)[4] |
| Effect of moisture on strength | Polymaker's printed dry-versus-wet blocks for its CoPA nylon show what conditioning does to the family: tensile 78.0 → 34.3 MPa and modulus 2703 → 724 MPa, with notched Charpy rising 6.9 → 27.7 kJ/m². Fibre reinforcement reduces but does not remove the effect[12][13] | Siraya Tech publishes dry against saturated for the same grade: tensile 70 → 60 MPa, flexural 114 → 87 MPa, HDT at 1.8 MPa 73.5 → 48.5 °C, while Charpy rises 10 → 14.5 kJ/m²[4][5] |
| Storage requirement | Not documented | Dry box below 15 % RH (Siraya Tech)[4] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | Not documented | 72 at break (printed, ASTM D638, Siraya Tech); the product page quotes 70 dry and 60 saturated[4][5] |
| Young's modulusMPa | Not documented | 3600 (printed, ASTM D638, Siraya Tech)[4] |
| Elongation at break% | Not documented | 10.5 at break (printed, ASTM D638, Siraya Tech)[4] |
| Flexural strengthMPa | Not documented | 115 (printed, ISO 178, Siraya Tech); 114 dry against 87 saturated on the product page[4][5] |
| Flexural modulusMPa | Not documented | 3350 (printed, ISO 178, Siraya Tech)[4] |
| Charpy impact, notchedkJ/m² | Not documented | 10.1 Charpy (printed, ISO 179, Siraya Tech); the data sheet does not state whether the specimen was notched[4] |
| Brittleness1–5 | Not documented | Moderate — 10.5 % elongation at break puts it between PA6 and the fibre-filled grades[4] |
| Creep resistance / sustained load1–5 | Not documented | Good — Raise3D cites high creep resistance as a reason to choose the PPA matrix over other nylons[2] |
| Elasticity / flexibility1–5 | Not documented | Rigid — 3.6 GPa tensile modulus[4] |
| Wear resistance & friction | Not documented | Siraya Tech describes the unfilled grade as low-friction and self-lubricating, aimed at gears and bearings[4][5] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 81 dry and 61 saturated (printed, ISO 75 Method B at 0.45 MPa, Siraya Tech)[4] |
| HDT at 1.8 MPa°C | Not documented | 73.5 dry and 48.5 saturated (printed, ISO 75 Method A at 1.8 MPa, Siraya Tech) — unfilled PPA deflects near its Tg; the 190–227 °C figures quoted for PPA are carbon-filled grades[4][3] |
| Glass transition (Tg)°C | Not documented | 80 (ASTM D3418, Siraya Tech)[4] |
| Melting point / Vicat°C | Not documented | 231 melting point (ASTM D3418) and 230 Vicat (ISO 306), Siraya Tech[4] |
| Annealing response | Not documented | Siraya Tech's product page offers annealing for strength while its own data sheet says annealing is not recommended because the print can warp; on its 15 % carbon-filled PPA, annealing lifts HDT at 1.8 MPa from 82.5 to 119 °C[4][5][14] |
| Environment & Chemical | ||
| Chemical resistance | Not documented | Withstands fuels, oils and industrial chemicals; Bambu Lab rates semi-aromatic nylon better than general nylon against weak acids, weak alkalis and most organic solvents[4][3] |
| Water / humidity resistance in service1–5 | Not documented | Absorbs water, properties shift — a saturated specimen loses about 15 % of its tensile strength and 25 °C of heat-deflection temperature[4][5] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[15] | Not documented |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[15] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[15] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[15] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[15] | Not documented |
| Post-Processing | ||
| Support material pairing | Not documented | Compatible with quick-release support materials (Siraya Tech)[4] |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[16] | Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[16] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[16] | Mineral acids, oxidants, halogens and zinc chloride solutions attack the amide bond; ordinary solvents do not.[16] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[16] | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[16] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Raise3D Industrial PPA CF Technical Data Sheet V2.0 Raise3D · 2022-04 · tds
- Bambu Filament Technical Data Sheet V1.0 — PPA-CF Bambu Lab · 2026-08 · tds
- Siraya Tech Fibreheart PPA Technical Data Sheet Siraya Tech · 2026-08 · tds
- Siraya Tech Fibreheart PPA Filament — product page Siraya Tech · 2026-08 · vendor
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- Bambu Filament Technical Data Sheet V3.0 — PA6-CF Bambu Lab · 2026-08 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Siraya Tech Fibreheart PPA-CF Technical Data Sheet Siraya Tech · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds