3D Printing Info

Filament comparison

PA aramid vs PEKK

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA aramid vs PEKK — documented properties and sources
PropertyAramid-fibre nylonPAPEKKHIGHTEMP
Market snapshot
Listing priceUSD/kg; dated snapshotsNot documented$525.00/kg median; $332.50–$771.12/kg across 6 dated product listings
Identity & Market
Base polymer / chemistryAramid-fibre reinforced polyamide[1]Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3]
Densityg/cm³Not documented1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2]
Typical priceUSD/kgNot documented1 kg-equivalent spools cluster near 550[4][5][6]
Price range across brandsUSD/kgNot documented333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][5][6][7][8]
Market availability1–5Special order, 1–2 makers worldwide — no aramid-filled nylon filament was found in any catalogue searched; the aramid filaments that do exist in the retail market use an ASA matrix[9][4]Niche, a handful of specialist brands[4][5][6]
Spool sizes & diametersNot documented1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][5][3]
Typical applicationsNot documentedAerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3]
Printing Parameters
Bed temperature°CNot documented140 (3DXTech CarbonX PEKK-A CF15)[2]
Enclosure / chamber requirement1–5Enclosure required (passive) — as for every nylon[1]Actively heated chamber required[10][11]
Overall printing difficulty1–5Not documentedExpert / industrial hardware only[10][11]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — no aramid-filled nylon datasheet was obtainable; Polymaker measures about 9 h of brass nozzle life on its fibre-filled nylons[12]Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3]
Abrasiveness1–5Highly abrasive — fibre-reinforced nylon composite[12]Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles; nylon already needs a drybox and Prusa names kevlar among the fibres that raise nozzle-clogging risk[13]Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — the polyamide matrix governs uptake[15]Not documented
Effect of moisture on strengthPolymaker's printed dry-versus-wet blocks for its CoPA nylon show what conditioning does to the family: tensile 78.0 → 34.3 MPa and modulus 2703 → 724 MPa, with notched Charpy rising 6.9 → 27.7 kJ/m². Fibre reinforcement reduces but does not remove the effect[16][17]No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14]
Mechanical Properties
Tensile strength (XY)MPaNot documented86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Young's modulusMPaNot documented2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2]
Elongation at break%Not documented6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2]
Flexural strengthMPaNot documented136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Flexural modulusMPaNot documented3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2]
Other impact dataNot documentedIzod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3]
Layer adhesion / Z tensileMPaNot documented50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][18]
Brittleness1–5Not documentedModerate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2]
Creep resistance / sustained load1–5Not documentedExcellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3]
Elasticity / flexibility1–5Not documentedRigid[2]
Z strength as % of XY%Not documented56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][18]
Thermal Properties
HDT at 0.45 MPa°CNot documented158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2]
HDT at 1.8 MPa°CNot documented156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3]
Glass transition (Tg)°CNot documented156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2]
Melting point / Vicat°CNot documented300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2]
Thermal expansion (CTE)µm/m·KNot documented36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][18]
Environment & Chemical
UV resistance1–5Not documentedGood — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3]
Electrical & ESD propertiesNot documentedUnfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][18]
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[19]Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[19]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[19]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[19]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[19]Ventilated room or enclosure recommended[19]
Dust & fibre handling hazardNot documentedCarbon fibre is bound in the matrix; sanding dust should not be inhaled[2]
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[20]Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[20]Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[20]None — no solvent softens a polyaryletherketone.[21]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  2. CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  3. Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
  4. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  5. 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
  6. Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
  7. Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
  8. IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  9. Polymaker product catalogue Polymaker · 2026-08 · vendor
  10. Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
  11. Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
  12. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  13. Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
  14. THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
  15. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  16. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  17. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  18. Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
  19. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  20. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  21. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  22. The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper