Filament comparison
PA aramid vs PEKK
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | Aramid-fibre nylonPA | PEKKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | Not documented | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Aramid-fibre reinforced polyamide[1] | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3] |
| Densityg/cm³ | Not documented | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2] |
| Typical priceUSD/kg | Not documented | 1 kg-equivalent spools cluster near 550[4][5][6] |
| Price range across brandsUSD/kg | Not documented | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][5][6][7][8] |
| Market availability1–5 | Special order, 1–2 makers worldwide — no aramid-filled nylon filament was found in any catalogue searched; the aramid filaments that do exist in the retail market use an ASA matrix[9][4] | Niche, a handful of specialist brands[4][5][6] |
| Spool sizes & diameters | Not documented | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][5][3] |
| Typical applications | Not documented | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3] |
| Printing Parameters | ||
| Bed temperature°C | Not documented | 140 (3DXTech CarbonX PEKK-A CF15)[2] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive) — as for every nylon[1] | Actively heated chamber required[10][11] |
| Overall printing difficulty1–5 | Not documented | Expert / industrial hardware only[10][11] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — no aramid-filled nylon datasheet was obtainable; Polymaker measures about 9 h of brass nozzle life on its fibre-filled nylons[12] | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3] |
| Abrasiveness1–5 | Highly abrasive — fibre-reinforced nylon composite[12] | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles; nylon already needs a drybox and Prusa names kevlar among the fibres that raise nozzle-clogging risk[13] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[14] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — the polyamide matrix governs uptake[15] | Not documented |
| Effect of moisture on strength | Polymaker's printed dry-versus-wet blocks for its CoPA nylon show what conditioning does to the family: tensile 78.0 → 34.3 MPa and modulus 2703 → 724 MPa, with notched Charpy rising 6.9 → 27.7 kJ/m². Fibre reinforcement reduces but does not remove the effect[16][17] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[14] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | Not documented | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Young's modulusMPa | Not documented | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Elongation at break% | Not documented | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2] |
| Flexural strengthMPa | Not documented | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Flexural modulusMPa | Not documented | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Other impact data | Not documented | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3] |
| Layer adhesion / Z tensileMPa | Not documented | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][18] |
| Brittleness1–5 | Not documented | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2] |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3] |
| Elasticity / flexibility1–5 | Not documented | Rigid[2] |
| Z strength as % of XY% | Not documented | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][18] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2] |
| HDT at 1.8 MPa°C | Not documented | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3] |
| Glass transition (Tg)°C | Not documented | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Melting point / Vicat°C | Not documented | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Thermal expansion (CTE)µm/m·K | Not documented | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][18] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3] |
| Electrical & ESD properties | Not documented | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][18] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[19] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[19] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[19] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[19] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[19] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[19] | Ventilated room or enclosure recommended[19] |
| Dust & fibre handling hazard | Not documented | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[20] | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[21][22] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[20] | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[21] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[20] | None — no solvent softens a polyaryletherketone.[21] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper