3D Printing Info

Filament comparison

HIPS vs PVDF

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

HIPS vs PVDF — documented properties and sources
PropertyHIPSABSPVDFENGINEERING
Market snapshot
Listing priceUSD/kg; dated snapshots$29.99/kg median; $27.99–$32.00/kg across 3 dated product listings$250.67/kg median; $250.67–$250.67/kg across 1 dated product listings
Identity & Market
Base polymer / chemistryHigh-impact polystyrene — polystyrene toughened with a butadiene rubber phase[1][2]Polyvinylidene fluoride — a semi-crystalline fluoropolymer[3][4]
Densityg/cm³1.04 (ISO 1183)[1]1.71 (ISO 1183) — the densest unfilled filament in the dataset[3]
Typical priceUSD/kg1 kg spools cluster near 31[5][6]1 kg-equivalent spools cluster near 251[5]
Price range across brandsUSD/kg28–32 across brands; YXPOLYER 28, Push Plastic 30, 3DXTech 32[6][5][7]251 at 3DXTech's 750 g pricing — the most expensive material in the whole dataset[5]
Market availability1–5Available from several mainstream brands[5][6]Special order, 1–2 makers worldwide[5][8]
Spool sizes & diameters1.75 and 2.85 mm; 1 and 3 kg spools[6][5]1.75 and 2.85 mm; 750 g spools[5]
Typical applicationsBreak-away and d-limonene-soluble support for ABS and ASA, and a light model material in its own right[2]Chemical-plant fittings, semiconductor handling and parts needing outstanding UV and chemical resistance[3]
Printing Parameters
Nozzle temperature°C230–245 (Simplify3D)[9]Not documented
Bed temperature°C100–115 (Simplify3D)[9]70–110 (3DXTech FluorX)[3]
Enclosure / chamber requirement1–5Enclosure recommended[10]Enclosure required (passive)[3]
Part cooling fanPart cooling fan not required[9]Not documented
Bed surface & adhesion aidGlue stick, glass plate, Kapton tape or PET sheets[9]Not documented
Warping tendency1–5Moderate — needs adhesion aid or draught shield[10]High — enclosure needed for reliable large parts[3]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[9]Not documented
Stringing / oozing tendency1–5Slight — HIPS oozes less than ABS[9][11]Not documented
Overall printing difficulty1–5Intermediate — dry filament and a tuned profile[10]Expert / industrial hardware only[3][4]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely[10]Brass fine indefinitely for unfilled grades[3]
Abrasiveness1–5Non-abrasive[10]Non-abrasive when unfilled[3]
Nozzle clog risk1–5Low — no special hot-end required, no drybox and no hardened nozzle, and 3DXTech states drying is not needed[9][12][2]Low — 3DXTech lists no special nozzle concerns, no minimum layer height and states drying is not required[8]
Heat-creep / jam sensitivity1–5Slightly sensitive[9]Not documented
Hotend requirementNo special hot-end required[9]Not documented
Other hardware wearNot documentedHydrogen fluoride released on overheating is extremely corrosive and will attack hotend and enclosure metalwork as well as people[4]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Low (0.1–0.3 %) — Simplify3D lists water resistance as a headline property[9]Negligible (<0.1 % EMC) — fluoropolymers are essentially non-hygroscopic[3]
Symptoms when wetBubbling and popping at the nozzle, stringing and a rough surface[13]Not documented
Effect of moisture on strengthPolymaker rates ABS moderate-sensitivity and publishes no dry-versus-conditioned figures; absorbed water flashes to steam in the hotend and shows as bubbling and poor layer adhesion[13]Not applicable in practice — 3DXTech states drying is not required for PVDF, so there is no moisture-driven strength loss to measure[8]
Storage requirementSealed with desiccant; less critical than for the polyamides[13]Not documented
Mechanical Properties
Tensile strength (XY)MPa40 at break (printed XY, ISO 527)[1]51 at break (printed XY, ISO 527)[3]
Young's modulusMPa1350 (printed XY, ISO 527) — the lowest modulus of the styrenics here[1]2450 (printed XY, ISO 527)[3]
Elongation at break%18 at break (printed XY, ISO 527)[1]25 at break (printed XY, ISO 527)[3]
Flexural strengthMPa70 (printed XY, ISO 178)[1]50 (printed XY, ISO 178)[3]
Flexural modulusMPa1600 (printed XY, ISO 178)[1]1800 (printed XY, ISO 178)[3]
Other impact dataNot documentedIzod 133 J/m on extruded PVDF stock, converted from 2.49 ft-lb/in (ASTM D256)[14]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Tough — absorbs impact, yields before breaking[3]
Hardness (scale-specific)Shore A / Shore D / RockwellNot documentedRockwell M79 on extruded PVDF stock (ASTM D785)[14]
Creep resistance / sustained load1–5Moderate — no printed-HIPS creep test found; Tg of 100 °C keeps room-temperature service far below softening[1][9]Not documented
Fatigue / repeated-flex resistance1–5Moderate[1]Not documented
Elasticity / flexibility1–5Rigid[1]Slightly flexible in thin sections[3]
Thermal Properties
HDT at 0.45 MPa°CNot documented149 on extruded PVDF stock (ASTM D648 at 66 psi; converted from 300 °F)[14]
HDT at 1.8 MPa°CNot documented113 on extruded PVDF stock (ASTM D648 at 264 psi; converted from 235 °F)[14]
Glass transition (Tg)°C100 (DSC)[1]Not documented
Melting point / Vicat°CAmorphous — no melting point[1]170 melting (ISO 11357)[3]
Continuous service temperature°CBounded by a glass transition of 100 °C; no loaded-bar service figure is published for HIPS[1]149 long term and short term on extruded PVDF stock (converted from 300 °F)[14]
Thermal expansion (CTE)µm/m·KNot documented127.8 (extruded PVDF stock, ASTM D696; source states 7.1e-5 in/in/°F) — the highest thermal expansion of any engineering polymer in this dataset[14]
Flammability / UL 94Flammable; no UL 94 rating published[1]UL 94 V-0 on extruded PVDF stock; Ensinger lists inherent flame resistance[14]
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — polystyrene yellows and chalks under UV[15]Excellent — designed for permanent outdoor use; Ensinger lists good UV and weather resistance and high gamma radiation resistance for PVDF stock[3][14]
Chemical resistanceDissolves completely in d-limonene — the basis of its use as a soluble support[2]Outstanding — resistant to most acids, solvents and oxidising agents, which is the reason to use it[3]
Water / humidity resistance in service1–5Not documentedExcellent — essentially unaffected[3]
Food contactNot food safe[15]Not documented
Biodegradability / compostabilityNot biodegradable[15]Not documented
RecyclabilityNot accepted in household plastic collection[15]Not documented
Electrical & ESD propertiesSurface resistance above 10¹³ ohm/sq — insulating (ASTM D257)[1]Not documented
Health & Safety
Fume toxicity1–5High — hazardous VOC such as styrene; enclosure and filtration needed[16]Very high — toxic decomposition products; local exhaust mandatory. Above 315 °C thermal decomposition yields hydrofluoric acid, hydrogen cyanide and carbon monoxide[4]
VOC emission rateµg/min12–113 styrene, the range measured across ABS and the one HIPS filament tested[16]Not documented
Ultrafine-particle emission rateparticles/min≈4 × 10⁹ median for the HIPS filament tested, an order of magnitude below ABS but forty times PLA[16]Not documented
Hazardous species emittedStyrene was the only dominant VOC identified for the HIPS filament tested[16]Above 315 °C: hydrofluoric acid, hydrogen cyanide, phenols, carbon monoxide, carbon dioxide and dense smoke. HF is extremely corrosive, its skin burns may not be immediately visible or painful, and exposure can be fatal by skin absorption, inhalation or ingestion[4]
Ventilation / filtration requirement1–5Enclosure with carbon and HEPA filtration[16]Local exhaust to outside / fume hood — the SDS states local exhaust is preferred[4]
Dust & fibre handling hazardNot documentedMolten polymer causes thermal burns and must not be pulled off the skin. If HF is detected during a decomposition event, cut the heat but keep the extraction running, ventilate, and clear non-essential people from the area[4]
Post-Processing
Sanding & machiningSands and paints readily, like ABS[15]Not documented
Gluing & solvent weldingSolvent-welds with d-limonene, and with acetone via its polystyrene backbone[9][2]Not documented
Vapour / chemical smoothingd-limonene attacks the surface; acetone smoothing is far less effective than on ABS[2][9]Not documented
Support material pairingUsed as the support material itself — dissolves in d-limonene, or breaks away from ABS and ASA[2]Not documented
Dimensional accuracy & detailNot documentedThe processing window sits well below the 315 °C decomposition threshold, so nozzle temperature must be controlled rather than raised to chase flow[3][4]
Solvents & Solubility
Soluble ind-limonene, 12–24 h submerged with occasional agitation; acetone also dissolves it, and xylene does so at 23 °C.[17][18][19]THF, MEK, DMF, DMAc, NMP, DMSO and trimethyl phosphate dissolve 5–10 wt% at ambient — Arkema's active solvents, all lab reagents.[20]
Softened or crazed byLimonene also disrupts layer adhesion in some ABS and ASA grades, so an ABS model can flake apart in the same bath.[21]Acetone, MIBK, cyclohexanone, butyl acetate and glycol ethers swell it; alkalis above pH 12 attack the homopolymer.[20][22]
Solvent welding & smoothing agentLimonene welds and lightly etches it; acetone welds through the polystyrene backbone but smooths less well than ABS.[17][21]None for the workshop — the active solvents (NMP, DMAc, DMF) are laboratory reagents used for casting membranes, not joints.[20]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. 3DXMAX HIPS Technical Data Sheet 3DXTech · 2026-08 · tds
  2. 3DXMAX HIPS — product page 3DXTech · 2026-08 · vendor
  3. FluorX PVDF Technical Data Sheet v3 3DXTech · 2026-08 · tds
  4. FluorX PVDF Safety Data Sheet v1.1 3DXTech · 2026-08 · msds
  5. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  6. Push Plastic product catalogue Push Plastic · 2026-08 · vendor
  7. YXPOLYER HIPS product page YXPOLYER · 2026-08 · vendor
  8. FluorX PVDF — product page 3DXTech · 2026-08 · vendor
  9. HIPS — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  10. ABS / ASA / PC Usage Guide Bambu Lab Wiki · 2026-08 · doc
  11. ABS — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  12. Filament Material Guide Prusa Knowledge Base · 2026-08 · doc
  13. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  14. TECAFLON PVDF natural — stock shape properties Ensinger · 2026-08 · tds
  15. ABS — material basics Polymaker Wiki · 2026-08 · doc
  16. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  17. D-Limonene — FDM post-processing guide Filament2Print · 2026-08 · review
  18. Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
  19. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper
  20. Kynar PVDF — Design properties: solubility and irradiation (active and latent solvents) Arkema · 2026-08 · tds
  21. HIPS — Knowledge Base Prusa Research · 2026-08 · doc
  22. Kynar PVDF resin — chemical and fuel resistance Arkema · 2026-08 · tds