Filament comparison
BVOH vs PEKK
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | BVOH (soluble support)SUPPORT | PEKKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $165.72/kg median; $165.72–$165.72/kg across 1 dated product listings | $525.00/kg median; $332.50–$771.12/kg across 6 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Butenediol vinyl alcohol copolymer — a vinyl alcohol copolymer that dissolves faster and in cooler water than straight PVA[1] | Polyether ketone ketone, amorphous grade — a polyaryletherketone that stays amorphous, so it does not need PEEK's crystallisation control. Stratasys sells it as Antero 800NA and Antero 840CN03; category numbers below are unfilled unless a carbon grade is named[2][3] |
| Densityg/cm³ | Not documented | 1.28 unfilled (ASTM D792, Antero 800NA; 1.31 annealed) and 1.33 for CarbonX PEKK-A CF15 (ISO 1183)[3][2] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 166[1] | 1 kg-equivalent spools cluster near 550[4][5][6] |
| Price range across brandsUSD/kg | 166 at Fiberlogy's 500 g pricing on 3DJake[1] | 333-771 across grades and formats; 3DXTech CarbonX PEKK-A+CF15 333 at 2 kg, 3D4Makers unfilled PEKK-A 485 at 2 kg, IEMAI 3D 500 at 1 kg, Kimya PEKK Carbon 771 at 500 g[4][5][6][7][8] |
| Market availability1–5 | Niche, a handful of specialist brands[1] | Niche, a handful of specialist brands[4][5][6] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5 kg spools[1] | 1.75 and 2.85 mm; 200 g to 2 kg spools, plus Stratasys canisters[4][5][3] |
| Typical applications | Dissolvable support where PVA dissolves too slowly, and for materials PVA bonds to poorly[1] | Aerospace interior and structural parts; 3DXTech labels its carbon-filled PEKK-A grade AERO and Stratasys certifies Antero 800NA for outgassing and FST[2][3] |
| Printing Parameters | ||
| Bed temperature°C | Not documented | 140 (3DXTech CarbonX PEKK-A CF15)[2] |
| Enclosure / chamber requirement1–5 | Open frame is fine[9] | Actively heated chamber required[10][11] |
| Overall printing difficulty1–5 | Intermediate — dry filament and a tuned profile[12] | Expert / industrial hardware only[10][11] |
| Extruder requirement | A second extruder or a tool changer[9] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely[9] | Hardened steel required — the category spans unfilled PEKK, where brass is acceptable, and the carbon-filled aerospace grades that make up most of the market[2][3] |
| Abrasiveness1–5 | Non-abrasive[9] | Highly abrasive — most PEKK filament sold is carbon-filled; unfilled Antero 800NA and ThermaX PEKK-A are non-abrasive[2][3] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[12] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a mandatory 120 °C pre-dry before every print[13] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — the vinyl alcohol backbone is what makes it soluble[12][9] | Not documented |
| Effect of moisture on strength | Not a structural material; no dry-versus-conditioned data is published[12] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[13] |
| Storage requirement | Sealed with desiccant at all times[12] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | Not documented | 86.7-90.0 at yield and 73.0 at break (printed XZ, ASTM D638, Antero 800NA on the F900 and Fortus 450mc); 88.8 at break annealed; 126 at break for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Young's modulusMPa | Not documented | 2640-3870 (printed XZ, ASTM D638, Antero 800NA; upper figure annealed); 9125 for CarbonX PEKK-A CF15 (printed XY, ISO 527)[3][2] |
| Elongation at break% | Not documented | 6.1 at break (printed XZ, ASTM D638, Antero 800NA); 2.3 in ZX; 3.15 for CarbonX PEKK-A CF15 (ISO 527)[3][2] |
| Flexural strengthMPa | Not documented | 136 at 5 % strain (printed XZ, ASTM D790, Antero 800NA); 178 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Flexural modulusMPa | Not documented | 3200 (printed XZ, ASTM D790, Antero 800NA); 8817 for CarbonX PEKK-A CF15 (printed XY, ISO 178)[3][2] |
| Other impact data | Not documented | Izod notched 41.1 J/m XZ and 33.3 J/m ZX; unnotched 1730 J/m XZ against 203 J/m ZX (printed, ASTM D256/D4812, Antero 800NA)[3] |
| Layer adhesion / Z tensileMPa | Not documented | 50.1-59.4 at yield (printed ZX, ASTM D638, Antero 800NA); 56.0 for the ESD grade Antero 840CN03[3][14] |
| Brittleness1–5 | Not documented | Moderate unfilled — 6.1 % elongation at break in plane; brittle in the carbon-filled grades at 3.15 %[3][2] |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Antero 800NA still holds 82 % of its room-temperature ZX tensile strength at 104 °C and 63 % at 132 °C (printed, ASTM D638)[3] |
| Elasticity / flexibility1–5 | Not documented | Rigid[2] |
| Z strength as % of XY% | Not documented | 56-82 (Antero 800NA and 840CN03 printed on the F900 and Fortus 450mc, ZX against XZ tensile yield and break, ASTM D638)[3][14] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 158 (printed XY and ZX, ASTM D648 Method B at 66 psi, Antero 800NA); 285 for CarbonX PEKK-A CF15 (ISO 75 at 0.45 MPa)[3][2] |
| HDT at 1.8 MPa°C | Not documented | 156-157 (printed, ASTM D648 Method B at 264 psi, Antero 800NA); moulded 147[3] |
| Glass transition (Tg)°C | Not documented | 156 (ASTM D7426, Antero 800NA); 165 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Melting point / Vicat°C | Not documented | 300 melt point (ASTM D7426 peak heat, Antero 800NA); 305 for CarbonX PEKK-A CF15 (DSC)[3][2] |
| Thermal expansion (CTE)µm/m·K | Not documented | 36.1 in XY and 50.2 in ZX (printed, 40-140 °C, ASTM E831, Antero 800NA); 47.4 and 51.2 for the ESD grade Antero 840CN03[3][14] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Good — years with some colour shift. 1000 h of QUV cycling to ASTM G154 left Antero 800NA's yield strength unchanged at 57 MPa and raised stress at break 3.6 %[3] |
| Water / humidity resistance in service1–5 | Dissolves or disintegrates — by design[1] | Not documented |
| Electrical & ESD properties | Not documented | Unfilled PEKK is an insulator at above 1.4e14 ohm-cm (ASTM D257); CarbonX PEKK-A CF15 sits above 10^7 ohm/sq, and the Antero 840CN03 ESD grade is specified at 10^4-10^9 ohm-cm[3][2][14] |
| Health & Safety | ||
| Fume toxicity1–5 | Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[15] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[15] |
| Ventilation / filtration requirement1–5 | Open a window / occasional ventilation[15] | Ventilated room or enclosure recommended[15] |
| Dust & fibre handling hazard | Not documented | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Post-Processing | ||
| Support material pairing | This is the support material[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Water: about 1 g of BVOH per 20 g of water, several hours; warmer water is faster but must not be too hot.[16][1] | Concentrated sulphuric acid, as for PEEK; no common organic solvent touches a polyaryletherketone.[17][18] |
| Softened or crazed by | Nothing else — a vinyl alcohol copolymer resists organic solvents, so IPA or acetone will not touch it.[19] | Concentrated sulphuric acid and liquid Freon are the entries Ensinger marks not resistant; acetone, MEK and toluene do nothing.[17] |
| Solvent welding & smoothing agent | None — water is a removal solvent, not a welding one.[16] | None — no solvent softens a polyaryletherketone.[17] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberlogy BVOH Natural — product page 3DJake International · 2026-08 · vendor
- CarbonX Carbon Fiber PEKK-A CF15 Technical Data Sheet v1 3DXTech · 2026-08 · tds
- Antero 800NA — FDM Material Data Sheet (PEKK-based) Stratasys · 2025-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- Kimya PEKK-A Natural 1.75 mm 500 g igo3d · 2026-08 · vendor
- Kimya PEKK Carbon Grey 1.75 mm 500 g igo3d · 2026-08 · vendor
- IEMAI 3D PEKK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- THERMAX PEKK-A — product page (print recommendations) 3DXTech · 2026-08 · doc
- Antero 840CN03 — FDM Material Data Sheet (PEKK, ESD) Stratasys · 2024-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Water soluble (BVOH/PVA) — Knowledge Base Prusa Research · 2026-08 · doc
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Polyvinyl alcohol — KURARAY POVAL application guide Kuraray · 2026-08 · tds