Filament comparison
BVOH vs PEEK-CF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | BVOH (soluble support)SUPPORT | Fibre-reinforced PEEKHIGHTEMP |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $165.72/kg median; $165.72–$165.72/kg across 1 dated product listings | $597.50/kg median; $448.00–$695.00/kg across 5 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Butenediol vinyl alcohol copolymer — a vinyl alcohol copolymer that dissolves faster and in cooler water than straight PVA[1] | Short-fibre reinforced PEEK. 3DXTech's CarbonX grade is nominally 10 wt% carbon and its FibreX grade 20 wt% glass; LEHVOSS Luvocom 3F PEEK CF 9676 is 15 wt% carbon; Ensinger's machining stock runs to 30 wt% carbon[2][3][4][5] |
| Densityg/cm³ | Not documented | 1.39 (ISO 1183)[2] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 166[1] | 1 kg-equivalent spools span 448–972; the middle of the market is about 598[3][4][6] |
| Price range across brandsUSD/kg | 166 at Fiberlogy's 500 g pricing on 3DJake[1] | 448-972 across formats and filler types; IEMAI 3D CF-PEEK and GF-PEEK 448 at 1 kg, 3DXTech CarbonX PEEK+CF10 598 at 2 kg and FibreX PEEK+GF20 695 at 1 kg, Luvocom 3F PEEK CF 9676 648 at 2 kg[3][4][6][7] |
| Market availability1–5 | Niche, a handful of specialist brands[1] | Niche, a handful of specialist brands[3][4] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5 kg spools[1] | 1.75 and 2.85 mm; 200 g to 2 kg spools[3][4] |
| Typical applications | Dissolvable support where PVA dissolves too slowly, and for materials PVA bonds to poorly[1] | Stiff aerospace and oil-and-gas parts where PEEK alone is not rigid enough[2] |
| Printing Parameters | ||
| Enclosure / chamber requirement1–5 | Open frame is fine[8] | Actively heated chamber required[9][10] |
| Warping tendency1–5 | Not documented | Moderate — needs adhesion aid or draught shield; the fibre cuts PEEK's crystallisation shrinkage[2] |
| Overall printing difficulty1–5 | Intermediate — dry filament and a tuned profile[11] | Expert / industrial hardware only[9][10] |
| Extruder requirement | A second extruder or a tool changer[8] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely[8] | Hardened steel required[2] |
| Abrasiveness1–5 | Non-abrasive[8] | Highly abrasive — standard CF composite[2] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[11] | High — jams from moisture, heat creep or particles; 3DXTech adds a hardened 0.4 mm minimum nozzle and 0.25 mm layers to the mandatory 120 °C pre-dry[12][13] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — the vinyl alcohol backbone is what makes it soluble[11][8] | Not documented |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.06 in 24 h on extruded CF30 stock (ASTM D570)[5] |
| Effect of moisture on strength | Not a structural material; no dry-versus-conditioned data is published[11] | No dry-versus-conditioned figures are published; 3DXTech mandates a 120 °C, 4 h pre-dry before every print because trapped water flashes to steam at these nozzle temperatures[12] |
| Storage requirement | Sealed with desiccant at all times[11] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | Not documented | 105 at break (printed XY, ISO 527, CF10); 121 at yield on extruded CF30 stock (ASTM D638)[2][5] |
| Young's modulusMPa | Not documented | 8100 (printed XY, ISO 527, CF10) — more than double unfilled PEEK; 6343 on extruded CF30 stock (ASTM D638)[2][5] |
| Elongation at break% | Not documented | 3 at break (printed XY, ISO 527), against 28 for unfilled PEEK[2][14] |
| Flexural strengthMPa | Not documented | 136 (printed XY, ISO 178, CF10); 193 on extruded CF30 stock (ASTM D790)[2][5] |
| Flexural modulusMPa | Not documented | 8300 (printed XY, ISO 178, CF10); 7171 on extruded CF30 stock (ASTM D790)[2][5] |
| Other impact data | Not documented | Izod notched 61.9 J/m on extruded CF30 stock, converted from 1.16 ft-lb/in (ASTM D256)[5] |
| Brittleness1–5 | Not documented | Brittle — snaps with little warning; elongation falls from 28 % to 3 %[2][14] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell M107 on extruded PEEK-CF30 stock (ASTM D785), against M100 unfilled[5][15] |
| Creep resistance / sustained load1–5 | Not documented | Excellent — holds load for years. Ensinger rates carbon-fibre PEEK stock as very highly creep resistant and specifies 260 °C continuous service[5] |
| Fatigue / repeated-flex resistance1–5 | Not documented | Good. Victrex rates PEEK for long-term fatigue as well as creep; the fibre cuts elongation at break from 28 % to 3 %, which limits repeated large-strain flexing[16][2][14] |
| Elasticity / flexibility1–5 | Not documented | Rigid[2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 265 (printed XY, ISO 75 at 0.45 MPa, CarbonX PEEK+CF10) against 140 for unfilled PEEK[2][14] |
| HDT at 1.8 MPa°C | Not documented | 316 on extruded CF30 stock, converted from 600 °F at 264 psi (ASTM D648)[5] |
| Glass transition (Tg)°C | Not documented | 143 (DSC, CarbonX PEEK+CF10) — the fibre does not move the glass transition[2] |
| Melting point / Vicat°C | Not documented | 334 melting on extruded CF30 stock, converted from 633 °F[5] |
| Continuous service temperature°C | Not documented | 260 long-term on extruded CF30 stock, converted from 500 °F; 300 short term[5] |
| Thermal expansion (CTE)µm/m·K | Not documented | 14.4 (extruded PEEK-CF30 stock, ASTM D696; source states 0.80e-5 in/in/°F) — about a third of unfilled PEEK[5][15] |
| Flammability / UL 94 | Not documented | UL 94 V-0 on the base resin; Ensinger lists extruded PEEK-CF30 stock as inherently flame resistant[14][5] |
| Environment & Chemical | ||
| Water / humidity resistance in service1–5 | Dissolves or disintegrates — by design[1] | Not documented |
| Electrical & ESD properties | Not documented | Surface resistance above 10⁹ ohm/sq — not static-dissipative (ASTM D257)[2] |
| Health & Safety | ||
| Fume toxicity1–5 | Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[17] | Moderate — measurable VOCs and UFPs, ventilation advised. None of these polymers was in the chamber study, and all are processed far above the temperatures it covered[17] |
| Ventilation / filtration requirement1–5 | Open a window / occasional ventilation[17] | Ventilated room or enclosure recommended[17] |
| Dust & fibre handling hazard | Not documented | Carbon fibre is bound in the matrix; sanding dust should not be inhaled[2] |
| Post-Processing | ||
| Support material pairing | This is the support material[1] | Not documented |
| Solvents & Solubility | ||
| Soluble in | Water: about 1 g of BVOH per 20 g of water, several hours; warmer water is faster but must not be too hot.[18][1] | 95–98 wt% sulphuric acid dissolves the matrix at 40–70 °C and leaves the fibre. Nothing else touches PEEK.[19][20] |
| Softened or crazed by | Nothing else — a vinyl alcohol copolymer resists organic solvents, so IPA or acetone will not touch it.[21] | Concentrated nitric, hydrofluoric, hydrobromic and hydriodic acids attack it; DCM, DMSO and THF swell thin-walled sections.[22][20] |
| Solvent welding & smoothing agent | None — water is a removal solvent, not a welding one.[18] | None — no solvent softens PEEK, so parts are joined thermally or mechanically, never chemically.[22][20] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberlogy BVOH Natural — product page 3DJake International · 2026-08 · vendor
- CarbonX Carbon Fiber PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- 3D4Makers product catalogue 3D4Makers · 2026-08 · vendor
- TECAPEEK CF30 black (PEEK-CF30) — stock shape properties Ensinger · 2026-08 · tds
- IEMAI 3D CF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- IEMAI 3D GF-PEEK 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Prusament PEI 1010 Technical Datasheet v1.0 Prusa Polymers · 2024-09 · tds
- Prusament PEI 1010 — material page Prusa Polymers · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- CARBONX PEEK+CF10 — product page (print recommendations) 3DXTech · 2026-08 · doc
- Composite materials filled with carbon, kevlar or glass Prusa Knowledge Base · 2026-08 · doc
- ThermaX PEEK Technical Data Sheet v3 3DXTech · 2026-08 · tds
- TECAPEEK natural (PEEK) — stock shape properties Ensinger · 2026-08 · tds
- PEEK polymers — product overview Victrex · 2026-08 · doc
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Water soluble (BVOH/PVA) — Knowledge Base Prusa Research · 2026-08 · doc
- The Effects of Sulfonated Poly(ether ether ketone) Ion Exchange Preparation Conditions on Membrane Properties Yee, Zhang & Ladewig, Membranes 3(3) 182–195 · 2013-07 · paper
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Polyvinyl alcohol — KURARAY POVAL application guide Kuraray · 2026-08 · tds
- What solvents are not compatible with PEEK? — fluidics technical FAQ IDEX Health & Science · 2026-08 · doc