Filament comparison
BVOH vs PC-FR
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | BVOH (soluble support)SUPPORT | Flame-retardant PC (PC-FR)PC |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $165.72/kg median; $165.72–$165.72/kg across 1 dated product listings | $87.50/kg median; $54.99–$224.00/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Butenediol vinyl alcohol copolymer — a vinyl alcohol copolymer that dissolves faster and in cooler water than straight PVA[1] | Flame-retardant polycarbonate. Polymaker builds its grade on Covestro's Makrolon family and rates it UL 94 V-0[2][3] |
| Densityg/cm³ | Not documented | 1.18 (Bambu Lab) and 1.2 (Polymaker), ISO 1183[3][2] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 166[1] | 1 kg-equivalent spools span 55–224; the two mainstream 1 kg grades are 55 and the industrial grades 120–224[3][4] |
| Price range across brandsUSD/kg | 166 at Fiberlogy's 500 g pricing on 3DJake[1] | 55–224 across brands; Bambu Lab and Polymaker 55, 3DXTech FR PC/ABS 120, 3DXLABS FR-PC 224[3][4][5] |
| Market availability1–5 | Niche, a handful of specialist brands[1] | Available from several mainstream brands[3][4][5] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5 kg spools[1] | 1.75 mm; 0.75 and 1 kg spools[4][5][3] |
| Typical applications | Dissolvable support where PVA dissolves too slowly, and for materials PVA bonds to poorly[1] | Electrical enclosures, transport interiors and battery housings that must meet a flammability rating[2][3] |
| Diameter tolerance± mm | Not documented | ±0.03 (Bambu Lab PC FR)[3] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 260–280 (Bambu Lab); 250–270 (Polymaker)[3][2] |
| Bed temperature°C | Not documented | 90–110 (Bambu Lab); 90–105 (Polymaker)[3][2] |
| Enclosure / chamber requirement1–5 | Open frame is fine[6] | Enclosure required (passive) — Bambu Lab specifies a 45–60 °C chamber, Polymaker 70–100 °C[3][2] |
| Recommended chamber temperature°C | Not documented | 45–60 (Bambu Lab); 70–100 (Polymaker)[3][2] |
| Part cooling fan | Not documented | 0–60 % (Bambu Lab)[3] |
| Bed surface & adhesion aid | Not documented | Smooth or textured PEI plate (Bambu Lab)[3] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | Not documented | 24 at Bambu Lab's 300 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[3][7] |
| Warping tendency1–5 | Not documented | Severe — heated chamber needed[2][8] |
| Bed-adhesion difficulty1–5 | Not documented | Needs a specific surface plus adhesive[9][10] |
| Stringing / oozing tendency1–5 | Not documented | Moderate — retraction tuning needed; Polymaker flags stringing as a common PC problem[10] |
| Overall printing difficulty1–5 | Intermediate — dry filament and a tuned profile[11] | Advanced — enclosure, hardware upgrades, tuning[3][8] |
| Extruder requirement | A second extruder or a tool changer[6] | Not documented |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely[6] | Brass fine indefinitely[8] |
| Abrasiveness1–5 | Non-abrasive[6] | Non-abrasive[2] |
| Nozzle clog risk1–5 | Very high — frequent jams without careful setup[11] | Moderate — needs dry filament and a clean nozzle; 3DXTech lists no special nozzle concerns but a 6 h pre-dry at 80 °C[12] |
| Heat-creep / jam sensitivity1–5 | Not documented | Slightly sensitive[9] |
| Hotend requirement | Not documented | All-metal hot end required (Simplify3D)[9] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Very high (>2 %) — the vinyl alcohol backbone is what makes it soluble[11][6] | Low (0.1–0.3 %) — 0.12 % saturated at 25 °C / 55 % RH (Bambu Lab), half that of unfilled Bambu Lab PC[3][13] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.12 saturated at 25 °C / 55 % RH (Bambu Lab)[3] |
| Drying temperature & time | Not documented | 75 °C for 6 h (Polymaker)[2] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle, stringing and a rough surface[11] |
| Effect of moisture on strength | Not a structural material; no dry-versus-conditioned data is published[11] | No dry-versus-conditioned figures are published. Polymaker calls PC highly hygroscopic and requires a 70–80 °C dry for 6–8 h; run wet, the loss shows as surface defects and poor layer adhesion[10][11] |
| Storage requirement | Sealed with desiccant at all times[11] | Airtight containers with desiccant to prevent reabsorption[10] |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | Not documented | 60 ± 4 (Bambu Lab) and 67 ± 4.5 (Polymaker) printed XY, ISO 527[3][2] |
| Young's modulusMPa | Not documented | 1670 ± 40 (Bambu Lab) and 2634 ± 182 (Polymaker) printed XY, ISO 527[3][2] |
| Elongation at break% | Not documented | 2.4 ± 0.3 (Bambu Lab) and 3.49 ± 0.7 (Polymaker) at break, printed XY, ISO 527 — the retardant roughly halves unfilled PC's elongation[3][2][14] |
| Flexural strengthMPa | Not documented | 96.6 ± 1.3 printed XY, ISO 178 (Polymaker)[2] |
| Flexural modulusMPa | Not documented | 2518 ± 53 printed XY, ISO 178 (Polymaker)[2] |
| Charpy impact, notchedkJ/m² | Not documented | 11.7 ± 1.6 printed XY, ISO 179, notched (Polymaker)[2] |
| Other impact data | Not documented | Notched Charpy 7.5 ± 1.6 kJ/m² at −30 °C printed XY (Polymaker, ISO 179-1/1eA)[2] |
| Layer adhesion / Z tensileMPa | Not documented | 21 ± 3 (Bambu Lab) and 46 ± 4.8 (Polymaker) printed Z, ISO 527[3][2] |
| Brittleness1–5 | Not documented | Moderate[3][2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell 70 (118) — the source does not name the scales and Shore D 79 on extruded unfilled PC stock (ASTM D785, D2240); no figure is published for a flame-retardant filament[15] |
| Creep resistance / sustained load1–5 | Not documented | Good. Moulded unfilled PC sustained 41 MPa tensile creep at room temperature without breaking, but the retardant package drops the glass transition to 115 °C in Polymaker's grade, so the unfilled rating is not carried over in full[16][2] |
| Elasticity / flexibility1–5 | Not documented | Rigid[2] |
| Z strength as % of XY% | Not documented | 35 (Bambu Lab) to 69 (Polymaker), printed[3][2] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 110 (Polymaker) and 113 (Bambu Lab), ISO 75 at 0.45 MPa[2][3] |
| HDT at 1.8 MPa°C | Not documented | 107 (Polymaker) and 108 (Bambu Lab), ISO 75 at 1.8 MPa[2][3] |
| Glass transition (Tg)°C | Not documented | 115 (Polymaker) and 145 (Bambu Lab), DSC[2][3] |
| Melting point / Vicat°C | Not documented | Amorphous — no melting point; Vicat 114 (Bambu Lab, ISO 306)[3] |
| Continuous service temperature°C | Not documented | 113 — Prusa publishes this as the temperature resistance of Prusament PC Blend[17] |
| Thermal expansion (CTE)µm/m·K | Not documented | 68.4 on extruded unfilled PC stock (ASTM D696; source states 3.8e-5 in/in/°F); no figure is published for a flame-retardant grade[15] |
| Flammability / UL 94 | Not documented | UL 94 V-0 (Polymaker PolyMax PC-FR); 3DXTech rates its FR PC/ABS V-0 at 1.5 mm on the base resin[2][18] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Degrades within weeks outdoors unless stabilised[10] |
| Chemical resistance | Not documented | Withstands oils, solvents and fuels; Polymaker rates it good against weak acids[10] |
| Water / humidity resistance in service1–5 | Dissolves or disintegrates — by design[1] | Not documented |
| Food contact | Not documented | Bisphenol-A polycarbonate is not offered as food-contact filament[10] |
| Biodegradability / compostability | Not documented | Not biodegradable[10] |
| Recyclability | Not documented | Mechanically recyclable but not accepted in household plastic collection[10] |
| Health & Safety | ||
| Fume toxicity1–5 | Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[19] | Moderate — measurable VOCs and UFPs, ventilation advised[19] |
| Ultrafine-particle emission rateparticles/min | Not documented | ≈4 × 10¹⁰ median — the highest ultrafine-particle rate of the nine filaments in the chamber study, above every ABS tested[19] |
| Ventilation / filtration requirement1–5 | Open a window / occasional ventilation[19] | Ventilated room or enclosure recommended[19][8] |
| Post-Processing | ||
| Sanding & machining | Not documented | Sands and machines well; the toughness means it cuts rather than chips[9] |
| Gluing & solvent welding | Not documented | Cyanoacrylate; dichloromethane solvent-welds PC but is a laboratory reagent[9] |
| Vapour / chemical smoothing | Not documented | No practical vapour smoothing[9] |
| Support material pairing | This is the support material[1] | Prints its own supports; 3DXTech sells a dedicated PC break-away support[9] |
| Solvents & Solubility | ||
| Soluble in | Water: about 1 g of BVOH per 20 g of water, several hours; warmer water is faster but must not be too hot.[20][1] | Dichloromethane, chloroform, DMF and dioxane dissolve it outright (Covestro, 6 days at 23 °C). Laboratory reagents.[21] |
| Softened or crazed by | Nothing else — a vinyl alcohol copolymer resists organic solvents, so IPA or acetone will not touch it.[22] | Methanol, butyl acetate, ether, 1 % NaOH and phthalate plasticisers stress-crack it; acetone, MEK and xylene swell it.[21] |
| Solvent welding & smoothing agent | None — water is a removal solvent, not a welding one.[20] | Dichloromethane cement welds PC — 16.5 MPa lap shear at one week (IPS Weld-On 3). A controlled carcinogen.[23] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberlogy BVOH Natural — product page 3DJake International · 2026-08 · vendor
- PolyMax PC-FR Technical Data Sheet V5.5 Polymaker · 2024-11 · tds
- Bambu Filament Technical Data Sheet V1.0 — PC FR Bambu Lab · 2026-08 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- ABS / ASA / PC Usage Guide Bambu Lab Wiki · 2026-08 · doc
- Polycarbonate — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- PC — material basics Polymaker Wiki · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- 3DXTech Firewire FR-PC/ABS product page 3DXTech · 2026-08 · vendor
- Bambu Filament Technical Data Sheet V2.0 — PC Bambu Lab · 2026-08 · tds
- PolyLite PC Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- TECANAT natural (PC) — stock shape properties Ensinger · 2026-08 · tds
- Experimental data for creep and dynamic mechanical properties of polycarbonate and polycarbonate/ABS Data in Brief 42:108264 · 2022-06 · paper
- Prusament PC Blend Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- Firewire Flame Retardant PC/ABS Technical Data Sheet Rev 3.0 3DXTech · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Water soluble (BVOH/PVA) — Knowledge Base Prusa Research · 2026-08 · doc
- Makrolon — The chemical resistance (Makrolon 2800, 6 days at 23 °C and 50 °C) Covestro · 2016-12 · tds
- Polyvinyl alcohol — KURARAY POVAL application guide Kuraray · 2026-08 · tds
- Weld-On 3 Acrylic Plastic Cement — technical data sheet (shipped as dichloromethane) IPS Corporation · 2002-07 · tds