Filament comparison
PCTG vs PVDF
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PCTGPETG | PVDFENGINEERING |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $34.99/kg median; $14.00–$50.67/kg across 5 dated product listings | $250.67/kg median; $250.67–$250.67/kg across 1 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Poly(cyclohexylenedimethylene terephthalate) glycol — a copolyester with a higher cyclohexanedimethanol content than PETG[1][2] | Polyvinylidene fluoride — a semi-crystalline fluoropolymer[3][4] |
| Densityg/cm³ | 1.23 (Extrudr, ASTM D792; 3DXTech, ISO 1183)[2][5] | 1.71 (ISO 1183) — the densest unfilled filament in the dataset[3] |
| Typical priceUSD/kg | 1 kg spools cluster near 34[6][5][7] | 1 kg-equivalent spools cluster near 251[8] |
| Price range across brandsUSD/kg | 14–51 across brands; CHCKX 14 in a 10-roll bundle, Push Plastic 30, Proto-pasta 35 at 1 kg, 3DXTech 51[6][5][9] | 251 at 3DXTech's 750 g pricing — the most expensive material in the whole dataset[8] |
| Market availability1–5 | Available from several mainstream brands[6][5][7][10] | Special order, 1–2 makers worldwide[8][11] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 0.5, 0.75, 1, 3 and 5 kg spools[6][7][5] | 1.75 and 2.85 mm; 750 g spools[8] |
| Typical applications | Transparent covers, guards and impact-loaded parts where PETG cracks[1][2] | Chemical-plant fittings, semiconductor handling and parts needing outstanding UV and chemical resistance[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 250–270 (Spectrum, Extrudr)[1][2] | Not documented |
| Bed temperature°C | 60–100 (Spectrum)[1] | 70–110 (3DXTech FluorX)[3] |
| Enclosure / chamber requirement1–5 | Open frame is fine — Spectrum and Extrudr both say a closed chamber is not necessary, Extrudr adds it helps on larger parts[1][2] | Enclosure required (passive)[3] |
| Part cooling fan | Up to 100 % (Spectrum); 20–50 % (Extrudr)[1][2] | Not documented |
| Bed surface & adhesion aid | Textured PEI, satin or powder-coated sheets; on smooth PEI a glue stick acts as a release agent[12][13] | Not documented |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 1.6–16 at the 20–200 mm/s Extrudr rates the material for, on a 0.4 mm nozzle at 0.2 mm layer[2][14] | Not documented |
| Warping tendency1–5 | Not documented | High — enclosure needed for reliable large parts[3] |
| Bed-adhesion difficulty1–5 | Needs the right surface or a thin adhesive — the problem is releasing the part, not sticking it[12][13] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed; Polymaker names stringing as PETG's common quirk[13] | Not documented |
| Shrinkage% | 0.2–0.5 (Extrudr, ASTM D955)[2] | Not documented |
| Overall printing difficulty1–5 | Easy — minor profile tuning[1][2] | Expert / industrial hardware only[3][4] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely — Extrudr explicitly states no hardened nozzle is needed[2] | Brass fine indefinitely for unfilled grades[3] |
| Abrasiveness1–5 | Non-abrasive[2] | Non-abrasive when unfilled[3] |
| Nozzle clog risk1–5 | Low — 3DXTech lists no special nozzle concerns and no minimum layer height for PCTG, only a 65 °C pre-dry[15] | Low — 3DXTech lists no special nozzle concerns, no minimum layer height and states drying is not required[11] |
| Heat-creep / jam sensitivity1–5 | Slightly sensitive[16] | Not documented |
| Hotend requirement | No special hot-end required[16] | Not documented |
| Other hardware wear | Not documented | Hydrogen fluoride released on overheating is extremely corrosive and will attack hotend and enclosure metalwork as well as people[4] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | Moderate (0.3–0.8 %) — the copolyester matrix reaches 0.40 % saturated at 25 °C / 55 % RH and 3DXTech specifies a 65 °C, 4 h pre-dry[12][15] | Negligible (<0.1 % EMC) — fluoropolymers are essentially non-hygroscopic[3] |
| Symptoms when wet | Bubbling and popping at the nozzle, stringing and a rough surface[17] | Not documented |
| Effect of moisture on strength | Polymaker groups PETG with nylon, PVA and TPU as highly hygroscopic; no dry-versus-conditioned strength figures are published for this grade and the loss shows as bubbling and poor layer adhesion[17] | Not applicable in practice — 3DXTech states drying is not required for PVDF, so there is no moisture-driven strength loss to measure[11] |
| Storage requirement | Sealed with desiccant; Polymaker groups PETG with the highly hygroscopic materials[17][13] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 43–44 at yield and 45–46 at break (ISO 527, injection-moulded resin data from Spectrum and Extrudr); 48 on My Tech Fun printed bars[1][2][18] | 51 at break (printed XY, ISO 527)[3] |
| Young's modulusMPa | Not documented | 2450 (printed XY, ISO 527)[3] |
| Elongation at break% | 215–220 at break on moulded specimens (ISO 527); 4.3–4.4 at yield[1][2] | 25 at break (printed XY, ISO 527)[3] |
| Flexural strengthMPa | Not documented | 50 (printed XY, ISO 178)[3] |
| Flexural modulusMPa | Not documented | 1800 (printed XY, ISO 178)[3] |
| Charpy impact, notchedkJ/m² | 93–94 notched Izod at 23 °C on moulded specimens (ISO 180); 3DXTech quotes 8 by ISO 180/A[1][2][5] | Not documented |
| Other impact data | Izod 4.14 kJ/m² on My Tech Fun printed bars, against 3.37 for PETG on the same rig[18] | Izod 133 J/m on extruded PVDF stock, converted from 2.49 ft-lb/in (ASTM D256)[19] |
| Layer adhesion / Z tensileMPa | 21.6 on My Tech Fun 4×4 mm printed bars, against 32.9 for PETG[18] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1][2] | Tough — absorbs impact, yields before breaking[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | 69 Shore D measured by My Tech Fun, against 72 for PETG[18] | Rockwell M79 on extruded PVDF stock (ASTM D785)[19] |
| Creep resistance / sustained load1–5 | Below average — a 12 mm bar sagged to 19.4 mm over 5 days at 1.25 kg, slightly worse than PETG's 18.2[18] | Not documented |
| Fatigue / repeated-flex resistance1–5 | Good — 215 % elongation at break and 94 kJ/m² notched Izod on moulded specimens (Extrudr, Spectrum)[1][2] | Not documented |
| Elasticity / flexibility1–5 | Slightly flexible in thin sections[18] | Slightly flexible in thin sections[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | Not documented | 149 on extruded PVDF stock (ASTM D648 at 66 psi; converted from 300 °F)[19] |
| HDT at 1.8 MPa°C | Not documented | 113 on extruded PVDF stock (ASTM D648 at 264 psi; converted from 235 °F)[19] |
| Glass transition (Tg)°C | 78 (3DXTech, DSC)[5] | Not documented |
| Melting point / Vicat°C | Amorphous — no melting point; Vicat 88 (Spectrum, Extrudr)[1][2] | 170 melting (ISO 11357)[3] |
| Continuous service temperature°C | 68 — loaded bars begin to move at this temperature, against 65 for PETG[18] | 149 long term and short term on extruded PVDF stock (converted from 300 °F)[19] |
| Thermal expansion (CTE)µm/m·K | Not documented | 127.8 (extruded PVDF stock, ASTM D696; source states 7.1e-5 in/in/°F) — the highest thermal expansion of any engineering polymer in this dataset[19] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for standard grades[20] | UL 94 V-0 on extruded PVDF stock; Ensinger lists inherent flame resistance[19] |
| Environment & Chemical | ||
| UV resistance1–5 | Not documented | Excellent — designed for permanent outdoor use; Ensinger lists good UV and weather resistance and high gamma radiation resistance for PVDF stock[3][19] |
| Chemical resistance | Withstands acids, alkalis, oils and UV exposure[13] | Outstanding — resistant to most acids, solvents and oxidising agents, which is the reason to use it[3] |
| Water / humidity resistance in service1–5 | Good — minor absorption; Spectrum describes the polymer as hydrophobic[1] | Excellent — essentially unaffected[3] |
| Food contact | Not certified for food contact as filament[13] | Not documented |
| Biodegradability / compostability | Not biodegradable[13] | Not documented |
| Recyclability | Not accepted in household plastic collection[13] | Not documented |
| Electrical & ESD properties | Surface resistance above 10¹³ ohm/sq — insulating (3DXTech, ASTM D257)[5] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[21] | Very high — toxic decomposition products; local exhaust mandatory. Above 315 °C thermal decomposition yields hydrofluoric acid, hydrogen cyanide and carbon monoxide[4] |
| Hazardous species emitted | Not documented | Above 315 °C: hydrofluoric acid, hydrogen cyanide, phenols, carbon monoxide, carbon dioxide and dense smoke. HF is extremely corrosive, its skin burns may not be immediately visible or painful, and exposure can be fatal by skin absorption, inhalation or ingestion[4] |
| Ventilation / filtration requirement1–5 | Open a window / occasional ventilation[21] | Local exhaust to outside / fume hood — the SDS states local exhaust is preferred[4] |
| Dust & fibre handling hazard | Not documented | Molten polymer causes thermal burns and must not be pulled off the skin. If HF is detected during a decomposition event, cut the heat but keep the extraction running, ventilate, and clear non-essential people from the area[4] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — the material is tough and gums rather than powders[16] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds PETG cleanly[16] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[16] | Not documented |
| Support material pairing | Prints its own supports; Polymaker rates PolyDissolve S1 for PETG[16] | Not documented |
| Dimensional accuracy & detail | Optical clarity is the selling point; Extrudr recommends a layer height at most 50 % of nozzle diameter[2] | The processing window sits well below the 315 °C decomposition threshold, so nozzle temperature must be controlled rather than raised to chase flow[3][4] |
| Solvents & Solubility | ||
| Soluble in | No common workshop solvent; Eastman's CHDM copolyester data shows 1,2-dichloroethane destroying it within a week.[22] | THF, MEK, DMF, DMAc, NMP, DMSO and trimethyl phosphate dissolve 5–10 wt% at ambient — Arkema's active solvents, all lab reagents.[23] |
| Softened or crazed by | Acetone, ethyl acetate, toluene and DMF swell and soften the copolyester; methanol crazes it (Eastman, 1 y at 23 °C).[22] | Acetone, MIBK, cyclohexanone, butyl acetate and glycol ethers swell it; alkalis above pH 12 attack the homopolymer.[23][24] |
| Solvent welding & smoothing agent | Dichloromethane brushed on is the only agent that smooths PETG — a controlled carcinogen, not workshop stock.[25] | None for the workshop — the active solvents (NMP, DMAc, DMF) are laboratory reagents used for casting membranes, not joints.[23] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Spectrum Premium PCTG Technical Data Sheet Spectrum Filaments · 2026-08 · tds
- Extrudr PCTG technical data Extrudr · 2026-08 · tds
- FluorX PVDF Technical Data Sheet v3 3DXTech · 2026-08 · tds
- FluorX PVDF Safety Data Sheet v1.1 3DXTech · 2026-08 · msds
- MAX-G PCTG Technical Data Sheet 3DXTech · 2026-08 · tds
- Push Plastic product catalogue Push Plastic · 2026-08 · vendor
- Proto-pasta product catalogue Proto-pasta · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- CHCKX 10KG Multicolor PCTG Filament bundle CHCKX (Amazon US) · 2026-08 · vendor
- Atomic Filament product catalogue Atomic Filament · 2026-08 · vendor
- FluorX PVDF — product page 3DXTech · 2026-08 · vendor
- Prusament PETG Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- PETG — material basics Polymaker Wiki · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- MAX-G PCTG — product page (print recommendations) 3DXTech · 2026-08 · doc
- PET and PETG — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PCTG vs PETG comparison — results spreadsheet My Tech Fun (Igor Gaspar) · 2026-08 · test
- TECAFLON PVDF natural — stock shape properties Ensinger · 2026-08 · tds
- Prusament PETG V0 Technical Datasheet Prusa Polymers · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Eastman Spectar copolyester — Chemical resistance (unstressed bars, 1 year at 23 °C) Eastman Chemical Company · 2026-08 · tds
- Kynar PVDF — Design properties: solubility and irradiation (active and latent solvents) Arkema · 2026-08 · tds
- Kynar PVDF resin — chemical and fuel resistance Arkema · 2026-08 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc