3D Printing Info

Filament comparison

PA6 vs PVB

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA6 vs PVB — documented properties and sources
PropertyPA6 (Nylon 6)PAPVBSPECIALTY
Market snapshot
Listing priceUSD/kg; dated snapshots$104.00/kg median; $38.99–$136.00/kg across 3 dated product listings$66.65/kg median; $49.32–$79.98/kg across 3 dated product listings
Identity & Market
Base polymer / chemistryPolyamide 6, ring-opened from caprolactam — the most hygroscopic of the common nylons[1][2]Polyvinyl butyral — a printable thermoplastic whose surface can be smoothed with isopropyl alcohol instead of a hot solvent[3]
Densityg/cm³1.06 (ISO 1183, 3DXTech iOn PA6 alloy)[4]1.10 (Polymaker PolySmooth, ISO 1183); Prusament PVB 1.10[3][5]
Typical priceUSD/kg1 kg-equivalent spools span 39–136; the middle of the market is about 104, though budget unfilled PA6 has now arrived at 39[6][7]1 kg-equivalent spools cluster near 80[8][9]
Price range across brandsUSD/kg39–136 across brands; YXPOLYER 39, 3DXTech iOn Nylon 6 Alloy 104, WearX Nylon 6 136. Unfilled PA6 filament stays rare — most PA6 reaches the market glass- or carbon-filled[6][7]49–102 across brands; Polymaker PolySmooth 49 at 750 g, Prusament PVB 80–102 at 500 g[8][9]
Market availability1–5Niche, a handful of specialist brands[6]Available from several mainstream brands[8][9]
Spool sizes & diameters1.75 and 2.85 mm; 500 g and 750 g spools[6]1.75 and 2.85 mm; 0.5 and 0.75 kg spools[8][9]
Typical applicationsWear parts, bushings and gears where PA6's toughness and abrasion resistance matter more than dimensional stability[1]Display models and light guides where a layer-free surface matters more than strength[3]
Diameter tolerance± mmNot documented+/- 0.03 (Prusament PVB)[5]
Printing Parameters
Nozzle temperature°C220–260 (Polymaker); 225–265 (Simplify3D)[1][10]215 +/- 10 (Prusament PVB)[5]
Bed temperature°C70–100 (Polymaker); 70–90 (Simplify3D)[1][10]75 +/- 5 (Prusament PVB)[5]
Enclosure / chamber requirement1–5Enclosure required (passive)[11][1]Open frame is fine[3]
Part cooling fanPart cooling fan not required (Simplify3D)[10]100 % part cooling (Prusament PVB)[5]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[10][1]Smooth PEI sheet or satin sheet; Prusa states a brim is not generally necessary[5]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[10][1]Not documented
Stringing / oozing tendency1–5Moderate — retraction tuning needed[1]Not documented
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning; the filament must be kept dry throughout the print[1][12]Easy — minor profile tuning; it prints close to PLA[3]
Hardware Wear & Reliability
Nozzle hardness required1–4Brass fine indefinitely for unfilled grades[1]Brass fine indefinitely[3]
Abrasiveness1–5Non-abrasive when unfilled[1]Non-abrasive[3]
Nozzle clog risk1–5Very high — frequent jams without careful setup; wet nylon pops and cracks in the melt[13][12]Moderate — needs dry filament and a clean nozzle; Prusa calls PVB very prone to absorbing moisture and requires a 60 °C, 4 h dry before every print[14][12]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[10]Not documented
Hotend requirementMay require an all-metal hot end (Simplify3D)[10]Not documented
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5Very high (>2 %) — Polymaker groups nylon with PVA as the most moisture-prone class, and its own PA6-based composites reach 2.35–3.33 % equilibrium[12][15]Very high (>2 %) — 2.36 % equilibrium water absorption (Polymaker PolySmooth), above every PLA and PETG grade here[3]
Equilibrium moisture content at ~50 % RH%Not documented2.36 equilibrium water absorption (Polymaker PolySmooth); 2.09 for PolyCast; Prusament PVB takes up 0.18 in 24 h and 0.35 in 7 days at 24 °C and 22 % RH[3][16][5]
Drying temperature & time100 °C for 8 h (Polymaker CoPA); storage below 20 % RH[11][17]Maximum 60 °C for 4-8 h depending on how wet the filament is (Prusament PVB)[5]
Symptoms when wetPopping and cracking during extrusion, then defects that Polymaker describes as very hard to diagnose[13]Not documented
Effect of moisture on strengthMeasured dry against wet on printed specimens at 6.16 % moisture (Polymaker CoPA): tensile 78.0 → 34.3 MPa, Young's modulus 2703 → 724 MPa, flexural strength 109.8 → 22.6 MPa, while notched Charpy rises 6.9 → 27.7 kJ/m² and elongation 12.7 → 13.2 %[11][13]Polymaker publishes no dry-versus-conditioned figures; at 2.36 % equilibrium uptake the material has to be kept dry to print cleanly[3][12]
Storage requirementSealed below 20 % RH with desiccant; Polymaker says nylon often needs to stay in a dryer while printing[17][12]Sealed with desiccant[12]
Hydrolysis at melt temperaturePolymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[11][17]Not documented
Mechanical Properties
Tensile strength (XY)MPa62 at break (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned to 20 °C / 50 % RH gives 67.6 ultimate and 49.3 at yield printed XZ (ASTM D638)[4][18]51.8 ± 0.7 printed XY, ISO 527 (PolySmooth); 53.2 ± 1.1 for PolyCast; Prusament PVB gives 50 +/- 5 at yield printed horizontal (ISO 527-1) and 57 +/- 1 on the filament (ISO 527)[3][16][5]
Young's modulusMPa2110 (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 2232 printed XZ and 1817 ZX (ASTM D638)[4][18]2199 ± 43 printed XY and 2010 ± 69 printed Z, ISO 527 (PolySmooth); Prusament PVB gives 1700 +/- 100 in both print directions (ISO 527-1)[3][5]
Elongation at break%9 at break (printed XY, ISO 527, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 38 printed XZ against 3.2 in ZX (ASTM D638)[4][18]5.7 ± 0.5 printed XY, ISO 527 (PolyCast)[16]
Flexural strengthMPa78 (printed XY, ISO 178, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 97.2 printed XZ and 82 ZX (ASTM D790)[4][18]72 +/- 1 printed horizontal and 73 +/- 3 printed vertical, ISO 178 (Prusament PVB)[5]
Flexural modulusMPa2200 (printed XY, ISO 178, 3DXTech iOn PA6 alloy); Stratasys FDM Nylon 6 conditioned gives 2196 printed XZ and 1879 ZX (ASTM D790)[4][18]2233 ± 106 printed XY, ISO 178 (PolyCast); Prusament PVB gives 2200 +/- 100 horizontal and 2300 +/- 100 vertical (ISO 178)[16][5]
Charpy impact, notchedkJ/m²Not documented7 +/- 1 printed horizontal and 10 +/- 1 printed vertical, ISO 179-1 notched (Prusament PVB)[5]
Other impact dataIzod notched 106 J/m printed XZ against 43 J/m in ZX; unnotched 2873 against 192 J/m (Stratasys FDM Nylon 6, conditioned 20 °C / 50 % RH, ASTM D256 Method A) — a 15x anisotropy unnotched[18]Charpy unnotched 55 +/- 7 printed horizontal and 59 +/- 12 printed vertical (Prusament PVB, ISO 179-1)[5]
Layer adhesion / Z tensileMPa36.5 ultimate and 28.9 at yield printed ZX (Stratasys FDM Nylon 6, conditioned 20 °C / 50 % RH, ASTM D638)[18]26.3 ± 2.1 printed Z, ISO 527 (PolyCast); Prusament PVB gives 49 +/- 5 at yield printed vertical (ISO 527-1) and 9 +/- 1 on Prusa's interlayer adhesion test[16][5]
Brittleness1–5Tough — absorbs impact, yields before breaking[1]Moderate[3]
Hardness (scale-specific)Shore A / Shore D / RockwellShore D 86 and Rockwell 85 (108) — the source does not name the scales on extruded unfilled PA66 stock (ASTM D2240, D785); no figure is published for a PA6 filament[19]Shore D 77 (Prusa Polymers method)[5]
Creep resistance / sustained load1–5Moderate[1]Not documented
Fatigue / repeated-flex resistance1–5Excellent — living hinges viable[1]Not documented
Elasticity / flexibility1–5Semi-flexible[13]Rigid[3]
Z strength as % of XY%54 (Stratasys FDM Nylon 6 conditioned, ZX against XZ ultimate tensile, ASTM D638); 59 on the yield figures[18]98 (Prusament PVB, printed vertical against horizontal tensile yield, ISO 527-1: 49 +/- 5 against 50 +/- 5) — the most isotropic printed material in this dataset[5]
Wear resistance & friction3DXTech sells a dedicated wear-resistant PA6 grade; abrasion resistance is the usual reason to choose PA6 over PA12[6]Not documented
Thermal Properties
HDT at 0.45 MPa°CNot documented68 (PolySmooth) and 67 (PolyCast), ISO 75 at 0.45 MPa; Prusament PVB 63 (ISO 75 at 0.45 MPa)[3][16][5]
HDT at 1.8 MPa°C93 (Stratasys FDM Nylon 6, conditioned, ASTM D648 at 264 psi)[18]66 (PolySmooth) and 53 (PolyCast), ISO 75 at 1.8 MPa; Prusament PVB 58 (ISO 75 at 1.8 MPa)[3][16][5]
Glass transition (Tg)°C105 (DSC, 3DXTech iOn PA6 alloy)[4]70 (DSC) for both PolySmooth and PolyCast[3][16]
Melting point / Vicat°CNot documentedAmorphous — no melting point; Vicat 70 (PolySmooth) and 67 (PolyCast), ISO 306[3][16]
Thermal expansion (CTE)µm/m·K81.0 on extruded unfilled PA66 stock (ASTM D696; source states 4.5e-5 in/in/°F); no figure is published for a PA6 filament, and PA6 and PA66 expand almost identically[19]Not documented
Flammability / UL 94Flammable; no UL 94 rating published for the unfilled filament grades surveyed[4]Not documented
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows and chalks under UV[1]Not documented
Chemical resistanceWithstands oils, fuels and alkalis — the usual reason to choose a polyamide[1]Not documented
Water / humidity resistance in service1–5Absorbs water, properties shift — a conditioned part is measurably softer and larger than the same part dry[13][11]Not documented
Food contactPolymaker notes medical-grade variants exist, but standard filament is not food-contact certified[1]Not documented
Biodegradability / compostabilityNot biodegradable[1]Not documented
RecyclabilityMechanically recyclable but not accepted in household plastic collection[1]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[2]Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[2]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[2]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[2]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[2]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[2]Open a window / occasional ventilation[2]
Post-Processing
Sanding & machiningSands poorly — the toughness makes it gum rather than powder[10]Not documented
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[10]Not documented
Vapour / chemical smoothingNo practical vapour smoothing[10]Isopropyl alcohol vapour smoothing is the point of the material — Polymaker markets PolySmooth for hands-free post-processing to a layer-free surface[3]
Support material pairingPVA dissolves cleanly against nylon; Polymaker sells a break-away PolySupport for PA12[10]PolyDissolve S1 is rated for PVB (Polymaker)[20]
Dimensional accuracy & detailParts grow as they absorb moisture after printing; Polymaker declines to publish a standard dimensional allowance because it depends on geometry and infill[13]PolyCast is the investment-casting variant of the same chemistry — it burns out cleanly rather than being smoothed[16]
Solvents & Solubility
Soluble inDissolved at 23 °C by formic acid above ~50 %, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — laboratory reagents.[21]Isopropyl alcohol dissolves it; Prusa describes PVB as soluble only in IPA, and it is not water-soluble.[14]
Softened or crazed byZinc chloride solutions stress-crack it — 10 % marginal, 37 % not resistant; alcoholic calcium chloride dissolves it.[21]Not documented
Solvent welding & smoothing agentNone — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[21]Isopropyl alcohol: brushed or sprayed on for speed, or several hours in IPA vapour for a glass-like surface.[22][14]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  2. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  3. PolySmooth Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  4. iOn PA6-based Nylon Alloy Technical Data Sheet v2.0 3DXTech · 2026-08 · tds
  5. Prusament PVB Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
  6. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  7. YXPOLYER PA6 Black 1 kg — product page YXPOLYER · 2026-08 · vendor
  8. Polymaker product catalogue Polymaker · 2026-08 · vendor
  9. Printed Solid product catalogue Printed Solid · 2026-08 · vendor
  10. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  11. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  12. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  13. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  14. Prusament PVB — material page Prusa Polymers · 2026-08 · tds
  15. Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  16. PolyCast Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  17. PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
  18. FDM Nylon 6 — data sheet (conditioned 20 °C / 50 % RH) Stratasys · 2017-11 · tds
  19. TECAMID 66 natural (PA66) — stock shape properties Ensinger · 2026-08 · tds
  20. PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
  21. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  22. Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc