Filament comparison
PA12 vs PP
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | PA12 (Nylon 12)PA | Polypropylene (PP)POLYOLEFIN |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $64.33/kg median; $36.00–$170.67/kg across 3 dated product listings | $46.56/kg median; $31.99–$53.00/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Polyamide 12 — the longest-chain common nylon, with the fewest amide groups per unit mass and so the least moisture uptake[1][2] | Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[3][4] |
| Densityg/cm³ | 1.01 specific gravity (Stratasys FDM Nylon 12, ASTM D792)[5] | 0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[6] |
| Typical priceUSD/kg | 1 kg-equivalent spools span 36–171; the middle of the market is about 64[7][8] | 1 kg-equivalent spools span 27–53; the middle of the market is about 44[9][10][11][12] |
| Price range across brandsUSD/kg | 36–171 across brands; IEMAI 3D 36, Fiberlogy 64 at 3DJake, 3DXTech AmideX Nylon 12 171[7][13][8] | 27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[9][14][10][11][12] |
| Market availability1–5 | Available from several mainstream brands[7][13] | Available from several mainstream brands[14][10][9] |
| Spool sizes & diameters | 1.75 and 2.85 mm; 750 g and 1 kg spools[13][7] | 1.75 and 2.85 mm; 0.75 kg spools are common[10] |
| Typical applications | Dimensionally stable functional parts, ducting and living hinges where PA6 would move too much with humidity[1][15] | Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[3] |
| Printing Parameters | ||
| Nozzle temperature°C | 260–290 (Extrudr DURAPRO PA12)[16] | 210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[3] |
| Bed temperature°C | 110 (Extrudr DURAPRO PA12)[16] | Not documented |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[1] | Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[17][4] |
| Part cooling fan | Part cooling fan not required (Simplify3D)[18] | Part cooling fan required (Simplify3D)[17] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[18][1] | Packing tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[17][4] |
| Maximum volumetric flow (mm³/s; see test conditions)mm³/s | 12 at Extrudr's 150 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[16][19] | Not documented |
| Warping tendency1–5 | Not documented | High — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[6][20] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[18][1] | Very difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[6][4] |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[1] | Slight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[4] |
| Overall printing difficulty1–5 | Advanced — enclosure, hardware upgrades, tuning[1] | Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[4][6] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Brass fine indefinitely for unfilled grades[1] | Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[17] |
| Abrasiveness1–5 | Non-abrasive when unfilled[1] | Non-abrasive when unfilled[17] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[15][21] | Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[21][17] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[18] | Slightly sensitive[17] |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[18] | No special hot-end required (Simplify3D)[17] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — Polymaker's PA12-CF10 reaches 1.5 % equilibrium against 3.33 % for its PA6-GF25, and Polymaker developed the PA12 grade specifically for lower moisture sensitivity[2][15] | Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[6] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[6] |
| Drying temperature & time | 60–80 °C for 8–12 h (Extrudr DURAPRO PA12); 100 °C for 8 h (Polymaker CoPA)[16][22] | No drying step is published for PP; uptake is below the level that affects printing[6] |
| Symptoms when wet | Popping and cracking during extrusion, then hard-to-diagnose defects[15] | Bubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[4] |
| Effect of moisture on strength | Polymaker states its PA12 grade changes little between wet and dry, unlike its PA6-based materials; the CoPA dry-to-wet reference shows what the PA6-type response looks like[15][22] | Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[6][21] |
| Storage requirement | Sealed below 20 % RH with desiccant[21] | No special storage needed[6] |
| Hydrolysis at melt temperature | Polymaker requires a 100 °C dry for 8 h and storage below 20 % RH; no molecular-weight loss figure is published, and the published wet data is conditioning rather than melt hydrolysis[22][23] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 49.3 at yield and 33.4 at break printed XZ (Stratasys FDM Nylon 12, ASTM D638)[5] | 12 at yield (Formfutura Centaur PP, ASTM D638)[3] |
| Young's modulusMPa | 1510 printed XZ and 1250 ZX (Stratasys FDM Nylon 12, ASTM D638)[5] | 724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[24] |
| Elongation at break% | 30 at break printed XZ against 6.5 in ZX (Stratasys FDM Nylon 12, ASTM D638)[5] | Above 600 at break (Formfutura Centaur PP, ASTM D638)[3] |
| Flexural strengthMPa | Not documented | 31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[24] |
| Flexural modulusMPa | Not documented | 402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[3] |
| Charpy impact, notchedkJ/m² | 11 at +23 °C and 6.0 at -30 °C (Extrudr DuraPro PA12, ISO 179/1eA); unnotched does not break[16] | Not documented |
| Other impact data | Izod notched 138 J/m printed XZ against 71.0 J/m in ZX (Stratasys FDM Nylon 12, ASTM D256)[5] | Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[24] |
| Layer adhesion / Z tensileMPa | 41.8 at yield and 41.2 at break printed ZX (Stratasys FDM Nylon 12, ASTM D638) — higher than the XZ break figure, because XZ specimens draw and neck first[5] | Not documented |
| Brittleness1–5 | Tough — absorbs impact, yields before breaking[1] | Very ductile — bends far before failing[3] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Not documented | Rockwell R102 (and M95) on extruded PP stock (ASTM D785)[24] |
| Creep resistance / sustained load1–5 | Moderate — the long-chain polyamides hold load better than PLA but below PC[1] | Below average[3] |
| Fatigue / repeated-flex resistance1–5 | Excellent — living hinges viable. Stratasys sells FDM Nylon 12 specifically for repetitive-flex parts such as snap-fit clips and press-fit inserts on the strength of its fatigue properties[1][5] | Excellent — living hinges viable, the classic polypropylene application[3] |
| Elasticity / flexibility1–5 | Semi-flexible[15] | Semi-flexible[3] |
| Z strength as % of XY% | 85 (Stratasys FDM Nylon 12, ZX against XZ tensile yield, ASTM D638) — one of the least anisotropic unfilled filaments measured[5] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 94.7 printed XY and 91.9 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 66 psi)[5] | 74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[24] |
| HDT at 1.8 MPa°C | 84.3 printed XY and 75.3 in XZ/ZX (Stratasys FDM Nylon 12, ASTM D648 at 264 psi)[5] | Not documented |
| Glass transition (Tg)°C | 34.0 (Stratasys FDM Nylon 12, ASTM D7426 inflection point)[5] | Not documented |
| Melting point / Vicat°C | Vicat A 142 (Extrudr DURAPRO PA12, ISO 306)[16] | 205 ± 15 melting (Formfutura Centaur PP)[3] |
| Continuous service temperature°C | Bounded by a Vicat softening point of 142 °C (Extrudr DURAPRO PA12); no loaded-bar service figure is published[16] | Bounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[3][6] |
| Thermal expansion (CTE)µm/m·K | 84-103 printed (Stratasys FDM Nylon 12, ASTM E831: 84.4 in XY and 85.6 in XZ/ZX over -50 to 10 °C, 89.1 over 10-45 °C, 98.2 over 45-70 °C); Extrudr quotes 100 for DURAPRO PA12 (ISO 11359-2)[16][5] | Not documented |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the unfilled grades surveyed[16] | Flammable; no UL 94 rating published for the grades surveyed[6] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement[1] | Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[4] |
| Chemical resistance | Withstands oils, fuels and alkalis[1] | Excellent against acids, alkalis and most solvents — the usual reason to choose PP[4] |
| Water / humidity resistance in service1–5 | Good — minor absorption; the least moisture-sensitive of the common nylons[15] | Excellent — essentially unaffected[6] |
| Food contact | Not food-contact certified as filament[1] | Polypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[4] |
| Biodegradability / compostability | Not biodegradable[1] | Not biodegradable[4] |
| Recyclability | Mechanically recyclable but not accepted in household plastic collection[1] | Mechanically recyclable as resin code 5, but printed waste is not accepted in household collection[4] |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[25] | Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[25] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon; total VOC reached nearly 200 µg/min, the highest of the nine filaments tested[25] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median — low for ultrafine particles despite the highest VOC mass of any filament tested[25] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament — the largest single-VOC emission rate measured in the study[25] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[25] | Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[25] |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[18] | Sands poorly — the waxy surface loads abrasive paper[17] |
| Painting & finishing | Not documented | Paint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[4] |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[18] | Nothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[4] |
| Vapour / chemical smoothing | No practical vapour smoothing[18] | No practical vapour smoothing[17] |
| Support material pairing | Polymaker sells a break-away PolySupport matched to PA12[18] | Prints its own supports; no soluble support is rated for PP[17] |
| Dimensional accuracy & detail | Holds dimensions better than PA6 after conditioning — Polymaker singles its PA12 grade out on exactly this point[15] | Shrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[6] |
| Solvents & Solubility | ||
| Soluble in | Dissolved at 23 °C by formic acid, phenol, m-cresol, 96 % sulphuric acid or hexafluoroisopropanol — all laboratory reagents.[26][27] | None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[28][29] |
| Softened or crazed by | Not resistant to 10 % formic acid, phenol, chloroform or dichloromethane (Ensinger); zinc chloride stress-cracks nylon.[27][26] | Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[28] |
| Solvent welding & smoothing agent | None — nylon's only solvents are formic acid, phenol and HFIP, all of which degrade the part they wet.[26] | None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[28] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
- PP — material basics Polymaker Wiki · 2026-08 · doc
- FDM Nylon 12 — Material Data Sheet Stratasys · 2021-09 · tds
- Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Nylon PA12 — product listing 3DJake International · 2026-08 · vendor
- IEMAI 3D PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- SUNLU product catalogue SUNLU · 2026-08 · vendor
- Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
- Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
- IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- 3DXTech product catalogue 3DXTech · 2026-08 · vendor
- PP filament listing 3DJake International · 2026-08 · vendor
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
- Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
- Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- PolyMide CoPA — Technical Data Sheet page Polymaker Wiki · 2026-08 · tds
- TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Chemical resistance — resistance of Ensinger plastics to chemicals (DIN 50 014, 23/50) Ensinger · 2026-08 · tds
- Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
- US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper