3D Printing Info

Filament comparison

PA12-CF vs PP

Compare printing settings, strength, heat resistance, dated prices and sources.

2 selected · all documented properties

PA12-CF vs PP — documented properties and sources
PropertyCarbon-fibre PA12 (PA12-CF)PAPolypropylene (PP)POLYOLEFIN
Market snapshot
Listing priceUSD/kg; dated snapshots$109.98/kg median; $52.00–$180.00/kg across 4 dated product listings$46.56/kg median; $31.99–$53.00/kg across 4 dated product listings
Identity & Market
Base polymer / chemistryPA12 reinforced with chopped carbon fibre — Polymaker's grade is 10 wt%[1][2]Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[3][4]
Densityg/cm³1.06 (Polymaker Fiberon) and 1.16 (3DXTech), ISO 1183[1][2]0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[5]
Typical priceUSD/kg1 kg-equivalent spools span 52–180; the middle of the market is about 110[6][7][8]1 kg-equivalent spools span 27–53; the middle of the market is about 44[9][10][11][12]
Price range across brandsUSD/kg52–180 across brands; IEMAI 3D 52, YXPOLYER 80 at 500 g, Polymaker Fiberon 140, 3DXTech CarbonX 180[6][7][13][8]27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[9][14][10][11][12]
Market availability1–5Available from several mainstream brands[6][7]Available from several mainstream brands[14][10][9]
Spool sizes & diameters1.75 mm; 0.5, 0.75 and 2 kg spools[6][7]1.75 and 2.85 mm; 0.75 kg spools are common[10]
Typical applicationsStiff parts that must stay dimensionally stable in changing humidity — Polymaker sells this grade specifically on low moisture sensitivity[15][1]Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[3]
Printing Parameters
Nozzle temperature°C260–290 (Extrudr DURAPRO PA12 CF)[16]210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[3]
Bed temperature°C110 (Extrudr DURAPRO PA12 CF)[16]Not documented
Enclosure / chamber requirement1–5Enclosure required (passive)[17][1]Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[18][4]
Part cooling fanNot documentedPart cooling fan required (Simplify3D)[18]
Bed surface & adhesion aidPEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[19][17]Packing tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[18][4]
Maximum volumetric flow (mm³/s; see test conditions)mm³/s12 at Extrudr's 150 mm/s cap on a 0.4 mm nozzle at 0.2 mm layer[16][20]Not documented
Warping tendency1–5Not documentedHigh — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[5][21]
Bed-adhesion difficulty1–5Needs a specific surface plus adhesive[19]Very difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[5][4]
Stringing / oozing tendency1–5Moderate — retraction tuning needed[17]Slight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[4]
Overall printing difficulty1–5Advanced — enclosure, hardware upgrades, tuning[17]Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[4][5]
Hardware Wear & Reliability
Nozzle hardness required1–4Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA12-CF10 and recommends hardened steel or ruby[1]Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[18]
Abrasiveness1–5Highly abrasive — standard CF composite; Polymaker puts brass nozzle life at roughly 9 h on PA12-CF10[1]Non-abrasive when unfilled[18]
Nozzle clog risk1–5High — jams from moisture, heat creep or particles[22]Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[22][18]
Heat-creep / jam sensitivity1–5Moderate — good heatbreak cooling needed[19]Slightly sensitive[18]
Hotend requirementMay require an all-metal hot end (Simplify3D)[19]No special hot-end required (Simplify3D)[18]
Moisture Behaviour
Moisture absorption (hygroscopicity)1–5High (0.8–2 %) — 1.5 % equilibrium, the lowest of Polymaker's nylon composites and less than half its PA6-GF25[1][23]Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[5]
Equilibrium moisture content at ~50 % RH%1.5 equilibrium water absorption (Polymaker Fiberon PA12-CF10)[1]0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[5]
Drying temperature & time80–100 °C; storage below 20 % RH[22][1]No drying step is published for PP; uptake is below the level that affects printing[5]
Symptoms when wetNot documentedBubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[4]
Effect of moisture on strengthPolymaker's own dry/wet blocks for PA12-CF10 change little: at 2.92 % moisture tensile falls 77.4 → 71.7 MPa and modulus 3311 → 3132 MPa, against a halving for its PA6 grades[1][15]Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[5][22]
Storage requirementSealed below 20 % RH with desiccant[22]No special storage needed[5]
Hydrolysis at melt temperaturePolymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[24][25]Not documented
Mechanical Properties
Tensile strength (XY)MPa77.4 ± 1.1 printed XY dry (Polymaker Fiberon), 71.7 ± 0.7 conditioned to 2.92 % moisture, ISO 527; 3DXTech quotes 72 at break. Stratasys FDM Nylon 12CF spans 76.5-124 at break printed XZ across five machine and tip combinations (ASTM D638)[1][2][26]12 at yield (Formfutura Centaur PP, ASTM D638)[3]
Young's modulusMPa3311 ± 135 printed XY dry and 3132 ± 124 conditioned, ISO 527 (Polymaker Fiberon); 3DXTech quotes 8000. Stratasys FDM Nylon 12CF spans 7910-15400 printed XZ against 2130-3000 in ZX (ASTM D638)[1][2][26]724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[27]
Elongation at break%4.2 ± 0.4 printed XY dry and 5.3 ± 0.3 conditioned, ISO 527 (Polymaker Fiberon); 3DXTech quotes 2.1 at break[1][2]Above 600 at break (Formfutura Centaur PP, ASTM D638)[3]
Flexural strengthMPa90 (printed XY, 3DXTech, ISO 178). Stratasys FDM Nylon 12CF spans 152-200 printed XZ against 61-73 in ZX (ASTM D790)[2][26]31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[27]
Flexural modulusMPa7900 (printed XY, 3DXTech, ISO 178)[2]402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[3]
Charpy impact, notchedkJ/m²9.9 ± 0.7 printed XY dry and 10.2 ± 0.8 conditioned, ISO 179 notched (Polymaker Fiberon)[1]Not documented
Other impact dataIzod notched 102-138 J/m printed XZ against 22.4-45.5 J/m in ZX (Stratasys FDM Nylon 12CF, ASTM D256)[26]Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[27]
Layer adhesion / Z tensileMPa52.2 ± 0.8 printed Z dry (Polymaker Fiberon) — 67 % of XY, unusually isotropic for a filled nylon; 42.1 ± 1.8 conditioned. Stratasys FDM Nylon 12CF gives 32.7-38.4 at break printed ZX (ASTM D638)[1][26]Not documented
Brittleness1–5Moderate[1]Very ductile — bends far before failing[3]
Hardness (scale-specific)Shore A / Shore D / RockwellRockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a carbon-fibre PA12 filament[28]Rockwell R102 (and M95) on extruded PP stock (ASTM D785)[27]
Creep resistance / sustained load1–5Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA12 matrix takes up 1.5 % equilibrium moisture against PA6's several per cent, so a PA12-CF part drifts less in service[29][1]Below average[3]
Fatigue / repeated-flex resistance1–5Good. Stratasys sells unfilled FDM Nylon 12 specifically for repetitive-flex parts on the strength of its fatigue properties, and Ensinger reports improved fatigue strength for carbon-filled nylon compounds[29]Excellent — living hinges viable, the classic polypropylene application[3]
Elasticity / flexibility1–5Rigid[1]Semi-flexible[3]
Z strength as % of XY%31-50 (Stratasys FDM Nylon 12CF, ZX against XZ tensile at break, ASTM D638, five machine and tip combinations) against 67 (Polymaker Fiberon PA12-CF10, printed Z against XY)[1][26]Not documented
Thermal Properties
HDT at 0.45 MPa°C131 (ISO 75, 0.45 MPa, Polymaker Fiberon). Stratasys FDM Nylon 12CF gives 160 printed XY and 168 ZX, and 175 with unidirectional toolpaths (ASTM D648 at 66 psi)[1][26]74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[27]
HDT at 1.8 MPa°C105 (ISO 75, 1.8 MPa, Polymaker Fiberon). Stratasys FDM Nylon 12CF gives 130 printed XY and 154 ZX (ASTM D648 at 264 psi)[1][26]Not documented
Glass transition (Tg)°C55 (DSC, Polymaker Fiberon)[1]Not documented
Melting point / Vicat°C171 melting (DSC); Vicat 170.2 (ISO 306)[1]205 ± 15 melting (Formfutura Centaur PP)[3]
Continuous service temperature°CNot documentedBounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[3][5]
Thermal expansion (CTE)µm/m·KStratasys FDM Nylon 12CF gives 116 on XY-built and 37 on ZX-built specimens over -50 to 20 °C, rising to 181 (XY) and 46 (ZX) above the 37.5 °C glass transition (ASTM E831); Extrudr quotes 100 for DURAPRO PA12 CF (ISO 11359-2)[16][26]Not documented
Flammability / UL 94Flammable; no UL 94 rating published for the grades surveyed[24]Flammable; no UL 94 rating published for the grades surveyed[5]
Environment & Chemical
UV resistance1–5Months outdoors before embrittlement — unstabilised polyamide yellows under UV[17]Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[4]
Chemical resistanceWithstands oils, fuels and alkalis[17]Excellent against acids, alkalis and most solvents — the usual reason to choose PP[4]
Water / humidity resistance in service1–5Good — minor absorption; the most humidity-stable nylon composite here[15][1]Excellent — essentially unaffected[5]
Food contactNot food-contact certified as filament[17]Polypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[4]
Biodegradability / compostabilityNot biodegradable[17]Not biodegradable[4]
RecyclabilityNot accepted in household plastic collection[17]Mechanically recyclable as resin code 5, but printed waste is not accepted in household collection[4]
Electrical & ESD propertiesSurface resistivity above 10¹² ohm — insulating (Polymaker Fiberon, ANSI/ESD S11.11)[1]Not documented
Health & Safety
Fume toxicity1–5Moderate — measurable VOCs and UFPs, ventilation advised[30]Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[30]
VOC emission rateµg/minUp to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[30]Not documented
Ultrafine-particle emission rateparticles/min≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[30]Not documented
Hazardous species emittedCaprolactam, at up to 180 µg/min from nylon filament[30]Not documented
Ventilation / filtration requirement1–5Ventilated room or enclosure recommended[30]Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[30]
Dust & fibre handling hazardFibre is bound in the matrix; sanding dust should not be inhaled[24]Not documented
Post-Processing
Sanding & machiningSands poorly — gums rather than powders[19]Sands poorly — the waxy surface loads abrasive paper[18]
Painting & finishingNot documentedPaint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[4]
Gluing & solvent weldingCyanoacrylate; no common solvent welds polyamide[19]Nothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[4]
Vapour / chemical smoothingNo practical vapour smoothing[19]No practical vapour smoothing[18]
Support material pairingNot documentedPrints its own supports; no soluble support is rated for PP[18]
Dimensional accuracy & detailPolymaker's own conditioning test found PA12-CF10 was the only nylon that did not grow past its original size after moisture conditioning[15]Shrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[5]
Solvents & Solubility
Soluble inFormic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[31]None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[32][33]
Softened or crazed byZinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[31]Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[32]
Solvent welding & smoothing agentNone — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[31]None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[32]

Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.

Sources for this comparison

  1. Fiberon PA12-CF10 Technical Data Sheet V1.1 Polymaker · 2025-02 · tds
  2. CarbonX CF PA12 Technical Data Sheet v1 3DXTech · 2026-08 · tds
  3. Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
  4. PP — material basics Polymaker Wiki · 2026-08 · doc
  5. Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  6. Polymaker product catalogue Polymaker · 2026-08 · vendor
  7. 3DXTech product catalogue 3DXTech · 2026-08 · vendor
  8. IEMAI 3D CF-PA12 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  9. SUNLU product catalogue SUNLU · 2026-08 · vendor
  10. Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
  11. Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
  12. IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
  13. YXPOLYER PA12 CF 500 g — product page YXPOLYER · 2026-08 · vendor
  14. PP filament listing 3DJake International · 2026-08 · vendor
  15. Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
  16. Extrudr Product Catalogue (DURAPRO PA12 data block) Extrudr · 2025-03 · tds
  17. PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
  18. Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  19. Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
  20. Max volumetric speed Prusa Knowledge Base · 2026-08 · doc
  21. Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
  22. Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
  23. Fiberon PA6-GF25 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  24. Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
  25. PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
  26. FDM Nylon 12CF — Material Data Sheet Stratasys · 2025-09 · tds
  27. TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
  28. TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
  29. TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
  30. Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
  31. Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
  32. Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
  33. US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper