Filament comparison
PA-CF ESD vs PVB
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | ESD-safe CF nylonPA | PVBSPECIALTY |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $129.98/kg median; $129.98–$129.98/kg across 1 dated product listings | $66.65/kg median; $49.32–$79.98/kg across 3 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Carbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1] | Polyvinyl butyral — a printable thermoplastic whose surface can be smoothed with isopropyl alcohol instead of a hot solvent[2] |
| Densityg/cm³ | 1.10 (ISO 1183)[1] | 1.10 (Polymaker PolySmooth, ISO 1183); Prusament PVB 1.10[2][3] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 130[4] | 1 kg-equivalent spools cluster near 80[4][5] |
| Price range across brandsUSD/kg | 130 at Polymaker's 0.5 kg pricing[4] | 49–102 across brands; Polymaker PolySmooth 49 at 750 g, Prusament PVB 80–102 at 500 g[4][5] |
| Market availability1–5 | Special order, 1–2 makers worldwide[4] | Available from several mainstream brands[4][5] |
| Spool sizes & diameters | 1.75 mm; 0.5 kg spools[4] | 1.75 and 2.85 mm; 0.5 and 0.75 kg spools[4][5] |
| Typical applications | Electronics jigs and trays that also need nylon toughness and heat resistance[1] | Display models and light guides where a layer-free surface matters more than strength[2] |
| Diameter tolerance± mm | Not documented | +/- 0.03 (Prusament PVB)[3] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 215 +/- 10 (Prusament PVB)[3] |
| Bed temperature°C | Not documented | 75 +/- 5 (Prusament PVB)[3] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[6] | Open frame is fine[2] |
| Part cooling fan | Not documented | 100 % part cooling (Prusament PVB)[3] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[7][6] | Smooth PEI sheet or satin sheet; Prusa states a brim is not generally necessary[3] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[7] | Not documented |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[6] | Not documented |
| Overall printing difficulty1–5 | Expert / industrial hardware only[6][8] | Easy — minor profile tuning; it prints close to PLA[2] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1] | Brass fine indefinitely[2] |
| Abrasiveness1–5 | Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1] | Non-abrasive[2] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[8] | Moderate — needs dry filament and a clean nozzle; Prusa calls PVB very prone to absorbing moisture and requires a 60 °C, 4 h dry before every print[9][8] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[7] | Not documented |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[7] | Not documented |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[10][11] | Very high (>2 %) — 2.36 % equilibrium water absorption (Polymaker PolySmooth), above every PLA and PETG grade here[2] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 2.36 equilibrium water absorption (Polymaker PolySmooth); 2.09 for PolyCast; Prusament PVB takes up 0.18 in 24 h and 0.35 in 7 days at 24 °C and 22 % RH[2][12][3] |
| Drying temperature & time | Not documented | Maximum 60 °C for 4-8 h depending on how wet the filament is (Prusament PVB)[3] |
| Effect of moisture on strength | Polymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][11] | Polymaker publishes no dry-versus-conditioned figures; at 2.36 % equilibrium uptake the material has to be kept dry to print cleanly[2][8] |
| Storage requirement | Sealed below 20 % RH with desiccant[8] | Sealed with desiccant[8] |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[13][14] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1] | 51.8 ± 0.7 printed XY, ISO 527 (PolySmooth); 53.2 ± 1.1 for PolyCast; Prusament PVB gives 50 +/- 5 at yield printed horizontal (ISO 527-1) and 57 +/- 1 on the filament (ISO 527)[2][12][3] |
| Young's modulusMPa | 4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1] | 2199 ± 43 printed XY and 2010 ± 69 printed Z, ISO 527 (PolySmooth); Prusament PVB gives 1700 +/- 100 in both print directions (ISO 527-1)[2][3] |
| Elongation at break% | 3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1] | 5.7 ± 0.5 printed XY, ISO 527 (PolyCast)[12] |
| Flexural strengthMPa | Not documented | 72 +/- 1 printed horizontal and 73 +/- 3 printed vertical, ISO 178 (Prusament PVB)[3] |
| Flexural modulusMPa | Not documented | 2233 ± 106 printed XY, ISO 178 (PolyCast); Prusament PVB gives 2200 +/- 100 horizontal and 2300 +/- 100 vertical (ISO 178)[12][3] |
| Charpy impact, notchedkJ/m² | 5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1] | 7 +/- 1 printed horizontal and 10 +/- 1 printed vertical, ISO 179-1 notched (Prusament PVB)[3] |
| Other impact data | Charpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1] | Charpy unnotched 55 +/- 7 printed horizontal and 59 +/- 12 printed vertical (Prusament PVB, ISO 179-1)[3] |
| Layer adhesion / Z tensileMPa | 21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1] | 26.3 ± 2.1 printed Z, ISO 527 (PolyCast); Prusament PVB gives 49 +/- 5 at yield printed vertical (ISO 527-1) and 9 +/- 1 on Prusa's interlayer adhesion test[12][3] |
| Brittleness1–5 | Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1] | Moderate[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[15] | Shore D 77 (Prusa Polymers method)[3] |
| Creep resistance / sustained load1–5 | Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[16][1] | Not documented |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[16] | Not documented |
| Elasticity / flexibility1–5 | Rigid[1] | Rigid[2] |
| Z strength as % of XY% | 26 (printed Z against XY tensile)[1] | 98 (Prusament PVB, printed vertical against horizontal tensile yield, ISO 527-1: 49 +/- 5 against 50 +/- 5) — the most isotropic printed material in this dataset[3] |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 157.0 (ISO 75, 0.45 MPa)[1] | 68 (PolySmooth) and 67 (PolyCast), ISO 75 at 0.45 MPa; Prusament PVB 63 (ISO 75 at 0.45 MPa)[2][12][3] |
| HDT at 1.8 MPa°C | 125.4 (ISO 75, 1.8 MPa)[1] | 66 (PolySmooth) and 53 (PolyCast), ISO 75 at 1.8 MPa; Prusament PVB 58 (ISO 75 at 1.8 MPa)[2][12][3] |
| Glass transition (Tg)°C | 41.8 (DSC)[1] | 70 (DSC) for both PolySmooth and PolyCast[2][12] |
| Melting point / Vicat°C | 187.3 melting (DSC); Vicat 190.0 (ISO 306)[1] | Amorphous — no melting point; Vicat 70 (PolySmooth) and 67 (PolyCast), ISO 306[2][12] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[13] | Not documented |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[6] | Not documented |
| Chemical resistance | Withstands oils, fuels and alkalis[6] | Not documented |
| Food contact | Not food-contact certified as filament[6] | Not documented |
| Biodegradability / compostability | Not biodegradable[6] | Not documented |
| Recyclability | Not accepted in household plastic collection[6] | Not documented |
| Electrical & ESD properties | Static-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][10] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[17] | Low hazard — minimal VOC and particle emission; none of these materials was in the chamber study[17] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[17] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[17] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[17] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[17] | Open a window / occasional ventilation[17] |
| Dust & fibre handling hazard | Fibre is bound in the matrix; sanding dust should not be inhaled[13] | Not documented |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[7] | Not documented |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[7] | Not documented |
| Vapour / chemical smoothing | No practical vapour smoothing[7] | Isopropyl alcohol vapour smoothing is the point of the material — Polymaker markets PolySmooth for hands-free post-processing to a layer-free surface[2] |
| Support material pairing | Not documented | PolyDissolve S1 is rated for PVB (Polymaker)[18] |
| Dimensional accuracy & detail | Not documented | PolyCast is the investment-casting variant of the same chemistry — it burns out cleanly rather than being smoothed[12] |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[19] | Isopropyl alcohol dissolves it; Prusa describes PVB as soluble only in IPA, and it is not water-soluble.[9] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[19] | Not documented |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[19] | Isopropyl alcohol: brushed or sprayed on for speed, or several hours in IPA vapour for a glass-like surface.[20][9] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
- PolySmooth Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Prusament PVB Technical Datasheet v1.1 Prusa Polymers · 2022-02 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- Printed Solid product catalogue Printed Solid · 2026-08 · vendor
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- Prusament PVB — material page Prusa Polymers · 2026-08 · tds
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- PolyCast Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- PolyDissolve S1 Technical Data Sheet V5.4 Polymaker · 2024-11 · tds
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Improve your 3D prints with chemical smoothing Prusa Research · 2026-08 · doc