Filament comparison
PA-CF ESD vs PP
Compare printing settings, strength, heat resistance, dated prices and sources.
2 selected · all documented properties
| Property | ESD-safe CF nylonPA | Polypropylene (PP)POLYOLEFIN |
|---|---|---|
| Market snapshot | ||
| Listing priceUSD/kg; dated snapshots | $129.98/kg median; $129.98–$129.98/kg across 1 dated product listings | $46.56/kg median; $31.99–$53.00/kg across 4 dated product listings |
| Identity & Market | ||
| Base polymer / chemistry | Carbon-filled polyamide compounded to a static-dissipative resistivity — Polymaker's grade uses a PA612 matrix[1] | Polypropylene — a semi-crystalline polyolefin with no polar groups, so it neither absorbs water nor bonds to most bed surfaces[2][3] |
| Densityg/cm³ | 1.10 (ISO 1183)[1] | 0.91 (Prusa PP composite, ISO 1183) — the lightest common filament[4] |
| Typical priceUSD/kg | 1 kg-equivalent spools cluster near 130[5] | 1 kg-equivalent spools span 27–53; the middle of the market is about 44[6][7][8][9] |
| Price range across brandsUSD/kg | 130 at Polymaker's 0.5 kg pricing[5] | 27–53 across brands; Reli3D 32 on Amazon, SUNLU 44 at 0.8 kg, Fiberlogy 49 at 750 g, IEMAI 3D 53, and the 3DJake PP listing spans 27–49[6][10][7][8][9] |
| Market availability1–5 | Special order, 1–2 makers worldwide[5] | Available from several mainstream brands[10][7][6] |
| Spool sizes & diameters | 1.75 mm; 0.5 kg spools[5] | 1.75 and 2.85 mm; 0.75 kg spools are common[7] |
| Typical applications | Electronics jigs and trays that also need nylon toughness and heat resistance[1] | Living hinges, chemical-resistant containers, automotive clips and packaging prototypes[2] |
| Printing Parameters | ||
| Nozzle temperature°C | Not documented | 210–230 (Braskem-type PE/PP window); Formfutura's Centaur PP melts at 205 ± 15 °C[2] |
| Enclosure / chamber requirement1–5 | Enclosure required (passive)[11] | Enclosure recommended — Simplify3D lists an enclosure as a hardware requirement and Polymaker advises one below 70 °C ambient to stop warping and cracking[12][3] |
| Part cooling fan | Not documented | Part cooling fan required (Simplify3D)[12] |
| Bed surface & adhesion aid | PEI sheet with a glue stick, or a dedicated adhesive such as Magigoo[13][11] | Packing tape, a polypropylene sheet, or a PP-specific adhesive such as Magigoo PP — ordinary PLA and ABS adhesives do not hold it[12][3] |
| Warping tendency1–5 | Not documented | High — enclosure needed for reliable large parts; PP's crystallinity drives shrinkage and Prusa recommends a brim on its PP grades[4][14] |
| Bed-adhesion difficulty1–5 | Needs a specific surface plus adhesive[13] | Very difficult — special plates or slurry required. PP bonds to almost nothing; a polypropylene-specific tape or adhesive is the normal answer[4][3] |
| Stringing / oozing tendency1–5 | Moderate — retraction tuning needed[11] | Slight — Polymaker advises 1–2 mm retraction at 20–30 mm/s[3] |
| Overall printing difficulty1–5 | Expert / industrial hardware only[11][15] | Advanced — enclosure, hardware upgrades, tuning; bed adhesion is the whole problem[3][4] |
| Hardware Wear & Reliability | ||
| Nozzle hardness required1–4 | Hardened steel required — Polymaker measures brass nozzle life at about 9 h on PA612-ESD and recommends hardened steel or ruby[1] | Brass fine indefinitely for unfilled grades — Simplify3D states no special hotend is required[12] |
| Abrasiveness1–5 | Highly abrasive — carbon-filled nylon composite; Polymaker puts brass nozzle life at roughly 9 h on PA612-ESD[1] | Non-abrasive when unfilled[12] |
| Nozzle clog risk1–5 | High — jams from moisture, heat creep or particles[15] | Low — Simplify3D lists no special hotend requirement for PP and clogging is not among its listed drawbacks[15][12] |
| Heat-creep / jam sensitivity1–5 | Moderate — good heatbreak cooling needed[13] | Slightly sensitive[12] |
| Hotend requirement | May require an all-metal hot end (Simplify3D)[13] | No special hot-end required (Simplify3D)[12] |
| Moisture Behaviour | ||
| Moisture absorption (hygroscopicity)1–5 | High (0.8–2 %) — the PA612 matrix sits between PA6 and PA12[16][17] | Negligible (<0.1 % EMC) — Prusa measures 0.03 % in 24 h and 0.04 % in 7 days on its PP composite, the lowest figures it publishes for any filament[4] |
| Equilibrium moisture content at ~50 % RH% | Not documented | 0.03 after 24 h and 0.04 after 7 days at 24 °C / 22 % RH (Prusa Polymers, measured on its PP composite)[4] |
| Drying temperature & time | Not documented | No drying step is published for PP; uptake is below the level that affects printing[4] |
| Symptoms when wet | Not documented | Bubbling and popping at the nozzle; Polymaker still advises a 70 °C dry for 4–6 h despite the low uptake[3] |
| Effect of moisture on strength | Polymaker publishes dry and wet printed blocks for PA612-ESD itself: at 4.64 % moisture tensile falls 84.3 → 73.6 MPa and modulus 4294 → 3731 MPa[1][17] | Not applicable in practice — with equilibrium uptake at 0.04 %, there is no moisture-driven strength loss to measure. Polymaker's sensitivity tiers put polyolefins below even PLA[4][15] |
| Storage requirement | Sealed below 20 % RH with desiccant[15] | No special storage needed[4] |
| Hydrolysis at melt temperature | Polymaker specifies an 80–100 °C dry and storage below 20 % RH; no molecular-weight loss figure is published, and the wet data it does publish is conditioning rather than melt hydrolysis[18][19] | Not documented |
| Mechanical Properties | ||
| Tensile strength (XY)MPa | 84.3 ± 2.3 printed XY dry (annealed 100 °C/16 h), 73.6 ± 2.3 conditioned to 4.64 % moisture, ISO 527[1] | 12 at yield (Formfutura Centaur PP, ASTM D638)[2] |
| Young's modulusMPa | 4293.7 ± 116.4 printed XY dry and 3730.8 ± 156.2 conditioned, ISO 527[1] | 724 on extruded PP stock (ASTM D638; converted from 105,000 psi)[20] |
| Elongation at break% | 3.0 ± 0.1 printed XY dry and 4.2 ± 0.4 conditioned, ISO 527[1] | Above 600 at break (Formfutura Centaur PP, ASTM D638)[2] |
| Flexural strengthMPa | Not documented | 31.0 on extruded PP stock (ASTM D790; converted from 4500 psi)[20] |
| Flexural modulusMPa | Not documented | 402 flexural modulus (Formfutura Centaur PP, ASTM D790) — an order of magnitude below any rigid filament[2] |
| Charpy impact, notchedkJ/m² | 5.9 ± 0.4 printed XY dry and 4.9 ± 0.3 conditioned, ISO 179 notched[1] | Not documented |
| Other impact data | Charpy unnotched 24.1 ± 2.4 printed XY and 4.5 ± 0.2 printed Z (ISO 179)[1] | Izod notched 112 J/m on extruded PP stock, converted from 2.1 ft-lb/in (ASTM D256)[20] |
| Layer adhesion / Z tensileMPa | 21.5 ± 2.7 printed Z dry — only a quarter of XY, the most anisotropic nylon composite here; 19.2 ± 1.6 conditioned[1] | Not documented |
| Brittleness1–5 | Brittle — snaps with little warning; elongation 3.0 % in XY and 1.4 % in Z[1] | Very ductile — bends far before failing[2] |
| Hardness (scale-specific)Shore A / Shore D / Rockwell | Rockwell M88 / R117 on extruded PA66-GF30 stock (ASTM D785); no figure is published for a conductive carbon-filled nylon filament[21] | Rockwell R102 (and M95) on extruded PP stock (ASTM D785)[20] |
| Creep resistance / sustained load1–5 | Good. Ensinger rates its PA66-CF30 compound for sustained static and dynamic load at 110 °C continuous service; the PA612 matrix here still takes up 4.64 % moisture at conditioning, which softens it[22][1] | Below average[2] |
| Fatigue / repeated-flex resistance1–5 | Good. Ensinger states carbon-filled PA66 compounds have improved fatigue strength in tension, flexure and compression[22] | Excellent — living hinges viable, the classic polypropylene application[2] |
| Elasticity / flexibility1–5 | Rigid[1] | Semi-flexible[2] |
| Z strength as % of XY% | 26 (printed Z against XY tensile)[1] | Not documented |
| Thermal Properties | ||
| HDT at 0.45 MPa°C | 157.0 (ISO 75, 0.45 MPa)[1] | 74 on extruded PP stock (ASTM D648 at 66 psi; converted from 165 °F)[20] |
| HDT at 1.8 MPa°C | 125.4 (ISO 75, 1.8 MPa)[1] | Not documented |
| Glass transition (Tg)°C | 41.8 (DSC)[1] | Not documented |
| Melting point / Vicat°C | 187.3 melting (DSC); Vicat 190.0 (ISO 306)[1] | 205 ± 15 melting (Formfutura Centaur PP)[2] |
| Continuous service temperature°C | Not documented | Bounded by a melting point of 205 ± 15 °C and by the 158 °C heat deflection of the carbon-filled grade; no loaded-bar service figure is published for unfilled PP[2][4] |
| Flammability / UL 94 | Flammable; no UL 94 rating published for the grades surveyed[18] | Flammable; no UL 94 rating published for the grades surveyed[4] |
| Environment & Chemical | ||
| UV resistance1–5 | Months outdoors before embrittlement — unstabilised polyamide yellows under UV[11] | Months outdoors before embrittlement — unstabilised polypropylene chalks under UV[3] |
| Chemical resistance | Withstands oils, fuels and alkalis[11] | Excellent against acids, alkalis and most solvents — the usual reason to choose PP[3] |
| Water / humidity resistance in service1–5 | Not documented | Excellent — essentially unaffected[4] |
| Food contact | Not food-contact certified as filament[11] | Polypropylene is a common food-packaging polymer, but no filament here carries a food-contact certification[3] |
| Biodegradability / compostability | Not biodegradable[11] | Not biodegradable[3] |
| Recyclability | Not accepted in household plastic collection[11] | Mechanically recyclable as resin code 5, but printed waste is not accepted in household collection[3] |
| Electrical & ESD properties | Static-dissipative — the reason the grade exists; Polymaker's insulating nylon composites sit above 10¹² ohm by contrast[1][16] | Not documented |
| Health & Safety | ||
| Fume toxicity1–5 | Moderate — measurable VOCs and UFPs, ventilation advised[23] | Low hazard — minimal VOC and particle emission. Inferred: no polyolefin was among the nine filaments in the Azimi chamber study, so this is a family-level judgement rather than a measurement[23] |
| VOC emission rateµg/min | Up to 180 caprolactam, the dominant VOC from nylon and the largest single-VOC rate in the study[23] | Not documented |
| Ultrafine-particle emission rateparticles/min | ≈2 × 10⁸ median for nylon — low for particles despite the highest VOC mass measured[23] | Not documented |
| Hazardous species emitted | Caprolactam, at up to 180 µg/min from nylon filament[23] | Not documented |
| Ventilation / filtration requirement1–5 | Ventilated room or enclosure recommended[23] | Open a window / occasional ventilation. Inferred — no polyolefin was measured in the chamber study[23] |
| Dust & fibre handling hazard | Fibre is bound in the matrix; sanding dust should not be inhaled[18] | Not documented |
| Post-Processing | ||
| Sanding & machining | Sands poorly — gums rather than powders[13] | Sands poorly — the waxy surface loads abrasive paper[12] |
| Painting & finishing | Not documented | Paint and adhesives do not key to untreated PP; flame or plasma treatment is normally needed first[3] |
| Gluing & solvent welding | Cyanoacrylate; no common solvent welds polyamide[13] | Nothing common bonds untreated PP; flame or plasma treatment is needed before adhesives key[3] |
| Vapour / chemical smoothing | No practical vapour smoothing[13] | No practical vapour smoothing[12] |
| Support material pairing | Not documented | Prints its own supports; no soluble support is rated for PP[12] |
| Dimensional accuracy & detail | Not documented | Shrinkage and warping dominate; the low modulus means parts flex rather than hold tolerance[4] |
| Solvents & Solubility | ||
| Soluble in | Formic acid, phenol, m-cresol and hexafluoroisopropanol dissolve the matrix at 23 °C, leaving the fibre; laboratory reagents.[24] | None at room temperature; chloroform dissolves it at 60 °C and xylene at about 118 °C — the xylene-solubles route.[25][26] |
| Softened or crazed by | Zinc chloride solutions stress-crack the nylon matrix, alcoholic calcium chloride dissolves it, mineral acids attack it.[24] | Xylene, decalin, CCl4 and chlorobenzene are heavily absorbed at 20 °C; oleum, chlorosulphonic acid and bromine destroy it.[25] |
| Solvent welding & smoothing agent | None — nylon's only solvents (formic acid, phenol, HFIP) degrade the part, and the fibre blocks surface flow anyway.[24] | None — nothing softens PP at room temperature, so joints have to be welded thermally rather than chemically.[25] |
Material entries describe families or representative grades, not an interchangeable specification for every spool. Test methods, orientations and conditions may differ. Unknown values are marked “Not documented”. Prices and source dates remain historical snapshots; check the linked guide for product details. Differences highlight text, not a universal winner.
Sources for this comparison
- Fiberon PA612-ESD Technical Data Sheet V1.0 Polymaker · 2025-06 · tds
- Centaur PP Technical Data Sheet Formfutura · 2026-08 · tds
- PP — material basics Polymaker Wiki · 2026-08 · doc
- Prusament PP Carbon Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Polymaker product catalogue Polymaker · 2026-08 · vendor
- SUNLU product catalogue SUNLU · 2026-08 · vendor
- Fiberlogy PP Natural — product page 3DJake International · 2026-08 · vendor
- Reli3D Low Warp PP Filament 1.75 mm 1 kg Black — Amazon listing Amazon.com · 2026-08 · vendor
- IEMAI 3D PP 3D Printing Filament — store page IEMAI 3D · 2026-08 · vendor
- PP filament listing 3DJake International · 2026-08 · vendor
- PA (Nylon) — material basics Polymaker Wiki · 2026-08 · doc
- Polypropylene — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Nylon — Ultimate 3D Printing Materials Guide Simplify3D · 2026-08 · doc
- Prusament PP Glass Fiber Technical Datasheet v1.0 Prusa Polymers · 2024-11 · tds
- Wet Filament — signs, causes and drying Polymaker Wiki · 2026-08 · doc
- Fiberon PA612-CF15 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- Moisture Conditioning — effect on printed nylon properties Polymaker Wiki · 2026-08 · doc
- Fiberon PA6-CF20 Technical Data Sheet V1.1 Polymaker · 2024-12 · tds
- PolyMide CoPA Technical Data Sheet V5.4 (dry and wet status blocks) Polymaker · 2024-11 · tds
- TECAFINE PP natural — stock shape properties Ensinger · 2026-08 · tds
- TECAMID 66 GF30 black (PA66-GF30) — stock shape properties Ensinger · 2026-08 · tds
- TECACOMP PA66 CF30 black — injection-moulding compound Ensinger · 2026-08 · tds
- Emissions of Ultrafine Particles and Volatile Organic Compounds from Commercially Available Desktop Three-Dimensional Printers with Multiple Filaments (Azimi et al.) Environmental Science & Technology 50(3) 1260-1268 · 2016-01 · paper
- Ultramid Nylon Chemical Resistance guide (unmodified PA6 B27E and PA66 A27E) BASF · 2026-08 · tds
- Pro-fax and Moplen polypropylene — Chemical Resistance Guide (20, 60 and 100 °C) LyondellBasell · 2026-08 · tds
- US 5,278,282 Polymer recycling by selective dissolution — xylene dissolution temperatures Nauman & Lynch, Rensselaer Polytechnic Institute · 1994-01 · paper